Coherent Reduction of Dipolar Interactions in Molecules Dissolved in Anisotropic Media Using a New Multiple-Pulse Sequence in a COSY Experiment

A new multipulse sequence, named Flip-Flop 16, which acts coherently on the spin Hamiltonian, is described. To avoid some of the technical difficulties encountered in multipulse experiments synchronized to the sampling of the magnetization, the sequence is applied during the t 1 period of a COSY exp...

Full description

Saved in:
Bibliographic Details
Published in:Journal of magnetic resonance. Series A 1994-04, Vol.107 (2), p.141-150
Main Authors: Lesot, P., Ouvrard, J.M., Ouvrard, B.N., Courtieu, J.
Format: Article
Language:English
Subjects:
Analytical chemistry
Atomic and molecular physics
Atomic, molecular and charged-particle sources and detectors
Chemical Sciences
Exact sciences and technology
Instruments, apparatus, components and techniques common to several branches of physics and astronomy
Molecular properties and interactions with photons
Nuclear resonance and relaxation
Physics
Citations: Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c349t-fa212b17744525a08320ef09342675e51b2bf358ab93ad46eb4c0971b6183ae43
cites
container_end_page 150
container_issue 2
container_start_page 141
container_title Journal of magnetic resonance. Series A
container_volume 107
creator Lesot, P.
Ouvrard, J.M.
Ouvrard, B.N.
Courtieu, J.
description A new multipulse sequence, named Flip-Flop 16, which acts coherently on the spin Hamiltonian, is described. To avoid some of the technical difficulties encountered in multipulse experiments synchronized to the sampling of the magnetization, the sequence is applied during the t 1 period of a COSY experiment. A scaled spectrum thus appears in the ν 1 dimension. An experimental study is presented using a simple A 2 spin system dissolved in a nematic liquid crystal. It is then demonstrated that the technique can be used to turn an AB deceptively simple or A 3B second-order spectrum into an AX or A 3X first-order spectrum, respectively.
doi_str_mv 10.1006/jmra.1994.1061
format article
fullrecord <record><control><sourceid>elsevier_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_02309080v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S1064185884710618</els_id><sourcerecordid>S1064185884710618</sourcerecordid><originalsourceid>FETCH-LOGICAL-c349t-fa212b17744525a08320ef09342675e51b2bf358ab93ad46eb4c0971b6183ae43</originalsourceid><addsrcrecordid>eNp1kDFP3DAYhqOqlUopa2cPLAw57NjxxePpgIJ0V6oCQyfri_MFjEwc7OTa_gr-cu0eYutk-9Xz-rOfovjC6IJRKk8fnwIsmFIiHSV7VxwwqmRJGyne570UJWvq5mPxKcZHSimTUhwUL2v_gAGHifzAbjaT9QPxPTmzo3cQyNUwYYB_cSR2IFvv0MwOYyJi9G6HXY5Xg41-Cn60hmyxs0Duoh3uCZBv-ItsZzfZ0WH5fXYRyQ0-zzgYzEUg6-ubn-T894jBPqVnfC4-9JCoo9f1sLi7OL9dX5ab669X69WmNFyoqeyhYlXLlksh6qoG2vCKYk8VF5Vc1liztmp7XjfQKg6dkNgKQ9WStZI1HFDww-Jkf-8DOD2m2RD-aA9WX642Ome04lTRhu5YYhd71gQfY8D-rcCozup1Vq-zep3Vp8LxvjBCNOD6AIOx8a0lGFeCq4Q1ewzTR3cWg47GZjOdDWgm3Xn7vwl_AX-Tl5I</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Coherent Reduction of Dipolar Interactions in Molecules Dissolved in Anisotropic Media Using a New Multiple-Pulse Sequence in a COSY Experiment</title><source>Elsevier SD Backfile Physics</source><creator>Lesot, P. ; Ouvrard, J.M. ; Ouvrard, B.N. ; Courtieu, J.</creator><creatorcontrib>Lesot, P. ; Ouvrard, J.M. ; Ouvrard, B.N. ; Courtieu, J.</creatorcontrib><description>A new multipulse sequence, named Flip-Flop 16, which acts coherently on the spin Hamiltonian, is described. To avoid some of the technical difficulties encountered in multipulse experiments synchronized to the sampling of the magnetization, the sequence is applied during the t 1 period of a COSY experiment. A scaled spectrum thus appears in the ν 1 dimension. An experimental study is presented using a simple A 2 spin system dissolved in a nematic liquid crystal. It is then demonstrated that the technique can be used to turn an AB deceptively simple or A 3B second-order spectrum into an AX or A 3X first-order spectrum, respectively.</description><identifier>ISSN: 1064-1858</identifier><identifier>EISSN: 1096-0864</identifier><identifier>DOI: 10.1006/jmra.1994.1061</identifier><language>eng</language><publisher>Orlando, FL: Elsevier Inc</publisher><subject>Analytical chemistry ; Atomic and molecular physics ; Atomic, molecular and charged-particle sources and detectors ; Chemical Sciences ; Exact sciences and technology ; Instruments, apparatus, components and techniques common to several branches of physics and astronomy ; Molecular properties and interactions with photons ; Nuclear resonance and relaxation ; Physics</subject><ispartof>Journal of magnetic resonance. Series A, 1994-04, Vol.107 (2), p.141-150</ispartof><rights>1994 Academic Press</rights><rights>1994 INIST-CNRS</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c349t-fa212b17744525a08320ef09342675e51b2bf358ab93ad46eb4c0971b6183ae43</citedby><orcidid>0000-0002-5811-7530</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S1064185884710618$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3632,27924,27925,46012</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=4139439$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-02309080$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Lesot, P.</creatorcontrib><creatorcontrib>Ouvrard, J.M.</creatorcontrib><creatorcontrib>Ouvrard, B.N.</creatorcontrib><creatorcontrib>Courtieu, J.</creatorcontrib><title>Coherent Reduction of Dipolar Interactions in Molecules Dissolved in Anisotropic Media Using a New Multiple-Pulse Sequence in a COSY Experiment</title><title>Journal of magnetic resonance. Series A</title><description>A new multipulse sequence, named Flip-Flop 16, which acts coherently on the spin Hamiltonian, is described. To avoid some of the technical difficulties encountered in multipulse experiments synchronized to the sampling of the magnetization, the sequence is applied during the t 1 period of a COSY experiment. A scaled spectrum thus appears in the ν 1 dimension. An experimental study is presented using a simple A 2 spin system dissolved in a nematic liquid crystal. It is then demonstrated that the technique can be used to turn an AB deceptively simple or A 3B second-order spectrum into an AX or A 3X first-order spectrum, respectively.</description><subject>Analytical chemistry</subject><subject>Atomic and molecular physics</subject><subject>Atomic, molecular and charged-particle sources and detectors</subject><subject>Chemical Sciences</subject><subject>Exact sciences and technology</subject><subject>Instruments, apparatus, components and techniques common to several branches of physics and astronomy</subject><subject>Molecular properties and interactions with photons</subject><subject>Nuclear resonance and relaxation</subject><subject>Physics</subject><issn>1064-1858</issn><issn>1096-0864</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1994</creationdate><recordtype>article</recordtype><recordid>eNp1kDFP3DAYhqOqlUopa2cPLAw57NjxxePpgIJ0V6oCQyfri_MFjEwc7OTa_gr-cu0eYutk-9Xz-rOfovjC6IJRKk8fnwIsmFIiHSV7VxwwqmRJGyne570UJWvq5mPxKcZHSimTUhwUL2v_gAGHifzAbjaT9QPxPTmzo3cQyNUwYYB_cSR2IFvv0MwOYyJi9G6HXY5Xg41-Cn60hmyxs0Duoh3uCZBv-ItsZzfZ0WH5fXYRyQ0-zzgYzEUg6-ubn-T894jBPqVnfC4-9JCoo9f1sLi7OL9dX5ab669X69WmNFyoqeyhYlXLlksh6qoG2vCKYk8VF5Vc1liztmp7XjfQKg6dkNgKQ9WStZI1HFDww-Jkf-8DOD2m2RD-aA9WX642Ome04lTRhu5YYhd71gQfY8D-rcCozup1Vq-zep3Vp8LxvjBCNOD6AIOx8a0lGFeCq4Q1ewzTR3cWg47GZjOdDWgm3Xn7vwl_AX-Tl5I</recordid><startdate>19940401</startdate><enddate>19940401</enddate><creator>Lesot, P.</creator><creator>Ouvrard, J.M.</creator><creator>Ouvrard, B.N.</creator><creator>Courtieu, J.</creator><general>Elsevier Inc</general><general>Academic Press</general><general>Elsevier - Academic Press [1993-1996]</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-5811-7530</orcidid></search><sort><creationdate>19940401</creationdate><title>Coherent Reduction of Dipolar Interactions in Molecules Dissolved in Anisotropic Media Using a New Multiple-Pulse Sequence in a COSY Experiment</title><author>Lesot, P. ; Ouvrard, J.M. ; Ouvrard, B.N. ; Courtieu, J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c349t-fa212b17744525a08320ef09342675e51b2bf358ab93ad46eb4c0971b6183ae43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1994</creationdate><topic>Analytical chemistry</topic><topic>Atomic and molecular physics</topic><topic>Atomic, molecular and charged-particle sources and detectors</topic><topic>Chemical Sciences</topic><topic>Exact sciences and technology</topic><topic>Instruments, apparatus, components and techniques common to several branches of physics and astronomy</topic><topic>Molecular properties and interactions with photons</topic><topic>Nuclear resonance and relaxation</topic><topic>Physics</topic><toplevel>online_resources</toplevel><creatorcontrib>Lesot, P.</creatorcontrib><creatorcontrib>Ouvrard, J.M.</creatorcontrib><creatorcontrib>Ouvrard, B.N.</creatorcontrib><creatorcontrib>Courtieu, J.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of magnetic resonance. Series A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lesot, P.</au><au>Ouvrard, J.M.</au><au>Ouvrard, B.N.</au><au>Courtieu, J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Coherent Reduction of Dipolar Interactions in Molecules Dissolved in Anisotropic Media Using a New Multiple-Pulse Sequence in a COSY Experiment</atitle><jtitle>Journal of magnetic resonance. Series A</jtitle><date>1994-04-01</date><risdate>1994</risdate><volume>107</volume><issue>2</issue><spage>141</spage><epage>150</epage><pages>141-150</pages><issn>1064-1858</issn><eissn>1096-0864</eissn><abstract>A new multipulse sequence, named Flip-Flop 16, which acts coherently on the spin Hamiltonian, is described. To avoid some of the technical difficulties encountered in multipulse experiments synchronized to the sampling of the magnetization, the sequence is applied during the t 1 period of a COSY experiment. A scaled spectrum thus appears in the ν 1 dimension. An experimental study is presented using a simple A 2 spin system dissolved in a nematic liquid crystal. It is then demonstrated that the technique can be used to turn an AB deceptively simple or A 3B second-order spectrum into an AX or A 3X first-order spectrum, respectively.</abstract><cop>Orlando, FL</cop><pub>Elsevier Inc</pub><doi>10.1006/jmra.1994.1061</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-5811-7530</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 1064-1858
ispartof Journal of magnetic resonance. Series A, 1994-04, Vol.107 (2), p.141-150
issn 1064-1858
1096-0864
language eng
recordid cdi_hal_primary_oai_HAL_hal_02309080v1
source Elsevier SD Backfile Physics
subjects Analytical chemistry
Atomic and molecular physics
Atomic, molecular and charged-particle sources and detectors
Chemical Sciences
Exact sciences and technology
Instruments, apparatus, components and techniques common to several branches of physics and astronomy
Molecular properties and interactions with photons
Nuclear resonance and relaxation
Physics
title Coherent Reduction of Dipolar Interactions in Molecules Dissolved in Anisotropic Media Using a New Multiple-Pulse Sequence in a COSY Experiment
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-03T23%3A23%3A22IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-elsevier_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Coherent%20Reduction%20of%20Dipolar%20Interactions%20in%20Molecules%20Dissolved%20in%20Anisotropic%20Media%20Using%20a%20New%20Multiple-Pulse%20Sequence%20in%20a%20COSY%20Experiment&rft.jtitle=Journal%20of%20magnetic%20resonance.%20Series%20A&rft.au=Lesot,%20P.&rft.date=1994-04-01&rft.volume=107&rft.issue=2&rft.spage=141&rft.epage=150&rft.pages=141-150&rft.issn=1064-1858&rft.eissn=1096-0864&rft_id=info:doi/10.1006/jmra.1994.1061&rft_dat=%3Celsevier_hal_p%3ES1064185884710618%3C/elsevier_hal_p%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c349t-fa212b17744525a08320ef09342675e51b2bf358ab93ad46eb4c0971b6183ae43%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true