Effect of Fe-doping on structural, magnetic and magnetocaloric properties of Nd0.67Ba0.33Mn1−xFexO3 manganites

• Published in: Ceramics international 2014-12, Vol.40 (10), p.16041-16050
• Main Authors: Hcini, Sobhi, Boudard, Michel, Zemni, Sadok, Oumezzine, Mohamed
• Format: Article
• Language: English
• Subjects: Chemical Sciences; Condensed Matter; Cooling; Doping; Entropy; Ferromagnetism; Glass; Iron; Magnetic and magnetocaloric properties; Magnetic properties; Manganites; Material chemistry; Physics; Spin glass; XRD analysis
• ISSN: 0272-8842; 1873-3956
• DOI: 10.1016/j.ceramint.2014.07.140

We have investigated the effect of Fe doping on structural, magnetic and magnetocaloric properties of Nd0.67Ba0.33Mn1−xFexO3 (0≤x≤0.1) manganites prepared by solid state reaction method at 1673K. XRD analysis shows that doping Mn by Fe do not affect the crystal structure of samples due to the same ionic radii of Fe3+ and Mn3+ and hence do not influence physical properties of samples. Magnetization measurements show a ferromagnetic behavior for x=0 and 0.02 samples, whereas compounds with x≥0.05 present a magnetic glass state (cluster or spin glass). The magnetic entropy change was also studied through the examination of measured magnetic isotherms M(H, T) near TC. The maximum magnetic entropy change (|ΔSMmax|) and the relative cooling power (RCP) are respectively 3.91 and 2.97JKg−1K−1 and 265 and 242JKg−1 at a field change of 5T, for x=0 and 0.02 samples. These values are compared favorably with those of some others reported manganites, making our samples promising candidates for the magnetic refrigeration. The field dependence of the magnetic entropy change analysis shows a power law dependence, ΔSM(H)=a(μ0H)n, with n=0.59 and 0.64 respectively for x=0 and 0.02 samples at their respective transition temperatures.