Germylene-sulfoxide as a potential hemilabile ligand: application in coordination chemistry

We describe here the synthesis of heteroleptic organogermylenes containing a sulfoxide donor function for their application in coordination chemistry. While complexation reaction with [W(cod)(CO)4] and [Mo(nbd)(CO)4] afforded bis(germanium)(ii) transition-metal complexes, a bidentate complex coordin...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2018-11, Vol.47 (44), p.15751-15756
Main Authors: Lentz, Nicolas, Mallet-Ladeira, Sonia, Baceiredo, Antoine, Kato, Tsuyoshi, Madec, David
Format: Article
Language:English
Subjects:
Chemical bonds
Chemical Sciences
Coordination chemistry
Coordination compounds
Crystallography
Organic chemistry
Sulfoxides
Transition metal compounds
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Summary:We describe here the synthesis of heteroleptic organogermylenes containing a sulfoxide donor function for their application in coordination chemistry. While complexation reaction with [W(cod)(CO)4] and [Mo(nbd)(CO)4] afforded bis(germanium)(ii) transition-metal complexes, a bidentate complex coordinated by germanium(ii) and the oxygen atom of the sulfinyl group was obtained from [Ru(PPh3)3Cl2].
ISSN:1477-9226
1477-9234
DOI:10.1039/c8dt03669a