Engineering Transport in Manganites by Tuning Local Nonstoichiometry in Grain Boundaries

Interface‐dominated materials such as nanocrystalline thin films have emerged as an enthralling class of materials able to engineer functional properties of transition metal oxides widely used in energy and information technologies. In particular, it has been proven that strain‐induced defects in gr...

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Bibliographic Details
Published in:Advanced materials (Weinheim) 2019-01, Vol.31 (4), p.e1805360-n/a
Main Authors: Chiabrera, Francesco, Garbayo, Iñigo, López‐Conesa, Lluis, Martín, Gemma, Ruiz‐Caridad, Alicia, Walls, Michael, Ruiz‐González, Luisa, Kordatos, Apostolos, Núñez, Marc, Morata, Alex, Estradé, Sonia, Chroneos, Alexander, Peiró, Francesca, Tarancón, Albert
Format: Article
Language:English
Subjects:
Cations
Composition
Condensed Matter
Crystal defects
Grain boundaries
Information technology
interface‐dominated materials
local nonstoichiometry
Manganites
Materials science
nanoionics
Physics
Properties (attributes)
Space charge
Thin films
Transition metal oxides
Transition metals
Transport properties
Tuning
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Summary:Interface‐dominated materials such as nanocrystalline thin films have emerged as an enthralling class of materials able to engineer functional properties of transition metal oxides widely used in energy and information technologies. In particular, it has been proven that strain‐induced defects in grain boundaries of manganites deeply impact their functional properties by boosting their oxygen mass transport while abating their electronic and magnetic order. In this work, the origin of these dramatic changes is correlated for the first time with strong modifications of the anionic and cationic composition in the vicinity of strained grain boundary regions. We are also able to alter the grain boundary composition by tuning the overall cationic content in the films, which represents a new and powerful tool, beyond the classical space charge layer effect, for engineering electronic and mass transport properties of metal oxide thin films useful for a collection of relevant solid‐state devices. Grain boundaries of strontium‐doped lanthanum manganite thin films are characterized by a strong modification of both anionic and cationic compositions. The grain boundary local nonstoichiometry can be altered by tuning the overall cationic content in the thin films, offering a tool to engineer the electronic and oxygen mass transport properties of these interfaces.
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.201805360