Transferability of Crystal-Field Parameters for Rare-Earth Ions in Y2SiO5 Tested by Zeeman Spectroscopy

Zeeman spectroscopy is used to demonstrate that phenomenological crystal-field parameters determined for the two C 1 point-group symmetry sites in Er 3+ :Y 2 SiO 5 may be transferred to other ions. The two crystallographic six-and seven-coordinate substitutional sites may be distinguished by compari...

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Bibliographic Details
Published in:Physics of the solid state 2019-05, Vol.61 (5), p.780-784
Main Authors: Jobbitt, N. L., Patchett, S. J., Alizadeh, Y., Reid, M. F., Wells, J.-P. R., Horvath, S. P., Longdell, J. J., Ferrier, A., Goldner, P.
Format: Article
Language:English
Subjects:
Chemical Sciences
Crystallography
Crystals
Impurity Centers
Material chemistry
Mathematical analysis
Metal ions
Parameters
Physics
Physics and Astronomy
Quantum Physics
Rare earth elements
Solid State Physics
Spectroscopy
Spectrum analysis
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Summary:Zeeman spectroscopy is used to demonstrate that phenomenological crystal-field parameters determined for the two C 1 point-group symmetry sites in Er 3+ :Y 2 SiO 5 may be transferred to other ions. The two crystallographic six-and seven-coordinate substitutional sites may be distinguished by comparing the spectra with crystal-field calculations.
ISSN:1063-7834
1090-6460
DOI:10.1134/S1063783419050123