Influence of weathering on visual and surface aspect of wood plastic composites: Correlation approach with mechanical properties and microstructure

• Published in: Polymer degradation and stability 2017-03, Vol.137, p.162-172
• Main Authors: Badji, Célia, Soccalingame, Lata, Garay, Hélène, Bergeret, Anne, Bénézet, Jean-Charles
• Format: Article
• Language: English
• Subjects: Aging (artificial); Aging (natural); Artificial weathering tests; Biomedical materials; Bleaching; Chain scission; Chemical properties; Chromatography; Cleavage; Color; Colorimetry; Composite materials; Engineering Sciences; Extrusion molding; Gloss; Injection molding; Leaching; Mechanical properties; Microcracks; Microstructure; Performance degradation; Polymer matrix composites; Polypropylene; Principal Component Analysis; Principal components analysis; Roughness; Studies; Visual observation; Weathering; Wood composites; Wood flour
• ISSN: 0141-3910; 1873-2321
• DOI: 10.1016/j.polymdegradstab.2017.01.010

This study aims to assess and understand simultaneously the changes in visual aspect, surface topography and mechanical properties of a wood flour reinforced polypropylene (PP) composite under natural and artificial weathering conditions. Compounds were produced through twin-screw extrusion followed by injection molding in order to obtain dog bone samples. A one-year natural outdoor exposure and a xenon-arc accelerated weathering were studied. As expected, mechanical performances are decreased under UV exposure. This performance degradation goes along with important changes in visual aspect. In addition to commonly used microscopy observations, other methods such as colorimetry, spectrogoniometry and confocal rugosimetry are used to characterize the surface aspect through color, gloss and roughness properties. These analyses revealed that ageing induces a surface bleaching, a wood particle protrusion and numerous micro-cracks. Moreover the chain scission attested by Size Exclusion Chromatography (SEC) and lixiviation on the surface induces roughness and gloss loss. Otherwise biocomposites were more degraded under natural weathering. This paper gives new insights in understanding how weathering affects physico-mechanical properties of wood plastic composites (WPC). For that, the Principal Component Analysis (PCA) gives global overview about effects of type of weathering and wood rate on physical, mechanical and chemical properties by calculating their contributions to the drawing of axes (Principal Components) during PCA.