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Mechanism of photochemical degradation of Fe(III)-EDDS complex
[Display omitted] •Fe(III)-EDDS complex is decomposed via a LMCT process under solar irradiation•EDDS degradation products are identified by HPLC-HRMS•Mechanisms with peroxy radicals can explain the formation of the identified products•EDDS is transformed into shorter oxidized products easily biodeg...
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Published in: | Journal of photochemistry and photobiology. A, Chemistry. Chemistry., 2020-08, Vol.399, p.112646, Article 112646 |
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container_title | Journal of photochemistry and photobiology. A, Chemistry. |
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creator | Jaber, S. Leremboure, M. Thery, V. Delort, A.-M. Mailhot, G. |
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•Fe(III)-EDDS complex is decomposed via a LMCT process under solar irradiation•EDDS degradation products are identified by HPLC-HRMS•Mechanisms with peroxy radicals can explain the formation of the identified products•EDDS is transformed into shorter oxidized products easily biodegradable•EDDS can be involved in AOPs used for water treatment without risk for environment
In this work, we investigated the photochemical degradation of the complex Fe(III)-EDDS which is increasingly used in studies of advanced oxidation processes. After irradiation of the aqueous solution, HPLC-HRMS analyses are used to identify the degradation products of EDDS. Six different products are separated and identified with specific chemical formulas. Proposed mechanisms based on the initial photo-redox process can explain the formation of all the products. They correspond to oxidized products with a shorter carbon chain and aldehyde and/or carboxylic acid functions. Among, them the formation of formaldehyde is also proposed in the mechanisms. This study is the first one that identifies degradation products of Fe(III)-EDDS complex and proposes a complete mechanism of degradation that can be applied for other iron complexes. |
doi_str_mv | 10.1016/j.jphotochem.2020.112646 |
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•Fe(III)-EDDS complex is decomposed via a LMCT process under solar irradiation•EDDS degradation products are identified by HPLC-HRMS•Mechanisms with peroxy radicals can explain the formation of the identified products•EDDS is transformed into shorter oxidized products easily biodegradable•EDDS can be involved in AOPs used for water treatment without risk for environment
In this work, we investigated the photochemical degradation of the complex Fe(III)-EDDS which is increasingly used in studies of advanced oxidation processes. After irradiation of the aqueous solution, HPLC-HRMS analyses are used to identify the degradation products of EDDS. Six different products are separated and identified with specific chemical formulas. Proposed mechanisms based on the initial photo-redox process can explain the formation of all the products. They correspond to oxidized products with a shorter carbon chain and aldehyde and/or carboxylic acid functions. Among, them the formation of formaldehyde is also proposed in the mechanisms. This study is the first one that identifies degradation products of Fe(III)-EDDS complex and proposes a complete mechanism of degradation that can be applied for other iron complexes.</description><identifier>ISSN: 1010-6030</identifier><identifier>EISSN: 1873-2666</identifier><identifier>DOI: 10.1016/j.jphotochem.2020.112646</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Chemical Sciences ; EDDS ; Iron complex ; Mass spectrometry ; Oxidation ; Photochemistry ; Radical chemistry</subject><ispartof>Journal of photochemistry and photobiology. A, Chemistry., 2020-08, Vol.399, p.112646, Article 112646</ispartof><rights>2020 Elsevier B.V.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c402t-49993df4b6edd1fc0402ce8e811858cb8d479cecd18444ed4fc4f2f88efb9d063</citedby><cites>FETCH-LOGICAL-c402t-49993df4b6edd1fc0402ce8e811858cb8d479cecd18444ed4fc4f2f88efb9d063</cites><orcidid>0000-0002-8179-8880 ; 0000-0002-6926-3242</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://hal.science/hal-02769495$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Jaber, S.</creatorcontrib><creatorcontrib>Leremboure, M.</creatorcontrib><creatorcontrib>Thery, V.</creatorcontrib><creatorcontrib>Delort, A.-M.</creatorcontrib><creatorcontrib>Mailhot, G.</creatorcontrib><title>Mechanism of photochemical degradation of Fe(III)-EDDS complex</title><title>Journal of photochemistry and photobiology. A, Chemistry.</title><description>[Display omitted]
•Fe(III)-EDDS complex is decomposed via a LMCT process under solar irradiation•EDDS degradation products are identified by HPLC-HRMS•Mechanisms with peroxy radicals can explain the formation of the identified products•EDDS is transformed into shorter oxidized products easily biodegradable•EDDS can be involved in AOPs used for water treatment without risk for environment
In this work, we investigated the photochemical degradation of the complex Fe(III)-EDDS which is increasingly used in studies of advanced oxidation processes. After irradiation of the aqueous solution, HPLC-HRMS analyses are used to identify the degradation products of EDDS. Six different products are separated and identified with specific chemical formulas. Proposed mechanisms based on the initial photo-redox process can explain the formation of all the products. They correspond to oxidized products with a shorter carbon chain and aldehyde and/or carboxylic acid functions. Among, them the formation of formaldehyde is also proposed in the mechanisms. This study is the first one that identifies degradation products of Fe(III)-EDDS complex and proposes a complete mechanism of degradation that can be applied for other iron complexes.</description><subject>Chemical Sciences</subject><subject>EDDS</subject><subject>Iron complex</subject><subject>Mass spectrometry</subject><subject>Oxidation</subject><subject>Photochemistry</subject><subject>Radical chemistry</subject><issn>1010-6030</issn><issn>1873-2666</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkE9PwzAMxSMEEmPwHXpkhw4nzbL0gjT2h1Ua4gCcoyxxaKp2mdpqgm9Pq6Jx5GTr2e_J_hESUZhSoOKhmBbHPLTB5FhNGbBOpkxwcUFGVM6TmAkhLrseKMQCErgmN01TAADnnI7I4wuaXB98U0XBReckb3QZWfystdWtD4d-uMH7LMsm8Xq1eotMqI4lft2SK6fLBu9-65h8bNbvy228e33OlotdbDiwNuZpmibW8b1Aa6kz0KkGJUpK5UyavbR8nho0lsruLLTcGe6YkxLdPrUgkjGZDLm5LtWx9pWuv1XQXm0XO9VrwOYi5ensRLtdOeyaOjRNje5soKB6ZqpQf8xUz0wNzDrr02DF7peTx1o1xuPBoPU1mlbZ4P8P-QG27Hko</recordid><startdate>20200801</startdate><enddate>20200801</enddate><creator>Jaber, S.</creator><creator>Leremboure, M.</creator><creator>Thery, V.</creator><creator>Delort, A.-M.</creator><creator>Mailhot, G.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-8179-8880</orcidid><orcidid>https://orcid.org/0000-0002-6926-3242</orcidid></search><sort><creationdate>20200801</creationdate><title>Mechanism of photochemical degradation of Fe(III)-EDDS complex</title><author>Jaber, S. ; Leremboure, M. ; Thery, V. ; Delort, A.-M. ; Mailhot, G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c402t-49993df4b6edd1fc0402ce8e811858cb8d479cecd18444ed4fc4f2f88efb9d063</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Chemical Sciences</topic><topic>EDDS</topic><topic>Iron complex</topic><topic>Mass spectrometry</topic><topic>Oxidation</topic><topic>Photochemistry</topic><topic>Radical chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jaber, S.</creatorcontrib><creatorcontrib>Leremboure, M.</creatorcontrib><creatorcontrib>Thery, V.</creatorcontrib><creatorcontrib>Delort, A.-M.</creatorcontrib><creatorcontrib>Mailhot, G.</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Journal of photochemistry and photobiology. A, Chemistry.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jaber, S.</au><au>Leremboure, M.</au><au>Thery, V.</au><au>Delort, A.-M.</au><au>Mailhot, G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mechanism of photochemical degradation of Fe(III)-EDDS complex</atitle><jtitle>Journal of photochemistry and photobiology. A, Chemistry.</jtitle><date>2020-08-01</date><risdate>2020</risdate><volume>399</volume><spage>112646</spage><pages>112646-</pages><artnum>112646</artnum><issn>1010-6030</issn><eissn>1873-2666</eissn><abstract>[Display omitted]
•Fe(III)-EDDS complex is decomposed via a LMCT process under solar irradiation•EDDS degradation products are identified by HPLC-HRMS•Mechanisms with peroxy radicals can explain the formation of the identified products•EDDS is transformed into shorter oxidized products easily biodegradable•EDDS can be involved in AOPs used for water treatment without risk for environment
In this work, we investigated the photochemical degradation of the complex Fe(III)-EDDS which is increasingly used in studies of advanced oxidation processes. After irradiation of the aqueous solution, HPLC-HRMS analyses are used to identify the degradation products of EDDS. Six different products are separated and identified with specific chemical formulas. Proposed mechanisms based on the initial photo-redox process can explain the formation of all the products. They correspond to oxidized products with a shorter carbon chain and aldehyde and/or carboxylic acid functions. Among, them the formation of formaldehyde is also proposed in the mechanisms. This study is the first one that identifies degradation products of Fe(III)-EDDS complex and proposes a complete mechanism of degradation that can be applied for other iron complexes.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.jphotochem.2020.112646</doi><orcidid>https://orcid.org/0000-0002-8179-8880</orcidid><orcidid>https://orcid.org/0000-0002-6926-3242</orcidid><oa>free_for_read</oa></addata></record> |
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source | ScienceDirect Freedom Collection 2022-2024 |
subjects | Chemical Sciences EDDS Iron complex Mass spectrometry Oxidation Photochemistry Radical chemistry |
title | Mechanism of photochemical degradation of Fe(III)-EDDS complex |
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