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Polarized micro-Raman study of Al2O3-based directionally solidified oxide eutectics containing GdAlO3 perovskite, Er3Al5O12 garnet and cubic ZrO2
The paper reports on the Raman signature of GdAlO3 perovskite and Er3Al5O12 garnet in melt‐grown eutectic composites, which contain α‐alumina and cubic zirconia also. Different wavelengths were used to discriminate the Raman signal from fluorescence of the rare‐earth elements. Fourteen out of the 24...
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Published in: | Journal of Raman spectroscopy 2010-09, Vol.41 (9), p.969-977 |
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container_title | Journal of Raman spectroscopy |
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creator | Gouadec, G. Makaoui, K. Perrière, L. Colomban, Ph Mazerolles, L. |
description | The paper reports on the Raman signature of GdAlO3 perovskite and Er3Al5O12 garnet in melt‐grown eutectic composites, which contain α‐alumina and cubic zirconia also. Different wavelengths were used to discriminate the Raman signal from fluorescence of the rare‐earth elements. Fourteen out of the 24 Raman active perovskite modes were identified. Mode symmetry is proposed for 12 of them, based on the polarization of the light backscattered by a rotated sample. Twenty‐one out of 25 Raman active modes of the garnet were listed and assigned by straight comparison with those of the parent compounds. Copyright © 2009 John Wiley & Sons, Ltd.
GdAlO3 perovskite and Er3Al5O12 garnet were studied by Raman microscopy in eutectic composites. Twelve GdAlO3 mode symmetries were proposed based on the backscattering from a rotated sample. Twenty‐one out of the 25 Raman active modes of Er3Al5O12 were assigned by comparison with those of the parent compounds. |
doi_str_mv | 10.1002/jrs.2523 |
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GdAlO3 perovskite and Er3Al5O12 garnet were studied by Raman microscopy in eutectic composites. Twelve GdAlO3 mode symmetries were proposed based on the backscattering from a rotated sample. Twenty‐one out of the 25 Raman active modes of Er3Al5O12 were assigned by comparison with those of the parent compounds.</description><identifier>ISSN: 0377-0486</identifier><identifier>ISSN: 1097-4555</identifier><identifier>EISSN: 1097-4555</identifier><identifier>DOI: 10.1002/jrs.2523</identifier><language>eng</language><publisher>Chichester, UK: John Wiley & Sons, Ltd</publisher><subject>alumina ; Backscattering ; Chemical Sciences ; Eutectics ; garnet ; Garnets ; Material chemistry ; Oxides ; perovskite ; Perovskites ; polarization ; Rare earth metals ; Wavelengths ; Zirconium dioxide</subject><ispartof>Journal of Raman spectroscopy, 2010-09, Vol.41 (9), p.969-977</ispartof><rights>Copyright © 2009 John Wiley & Sons, Ltd.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-8635-5069 ; 0000-0001-6099-5423 ; 0000-0003-3084-2383 ; 0000-0002-1476-2765</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://hal.science/hal-02932446$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Gouadec, G.</creatorcontrib><creatorcontrib>Makaoui, K.</creatorcontrib><creatorcontrib>Perrière, L.</creatorcontrib><creatorcontrib>Colomban, Ph</creatorcontrib><creatorcontrib>Mazerolles, L.</creatorcontrib><title>Polarized micro-Raman study of Al2O3-based directionally solidified oxide eutectics containing GdAlO3 perovskite, Er3Al5O12 garnet and cubic ZrO2</title><title>Journal of Raman spectroscopy</title><addtitle>J. Raman Spectrosc</addtitle><description>The paper reports on the Raman signature of GdAlO3 perovskite and Er3Al5O12 garnet in melt‐grown eutectic composites, which contain α‐alumina and cubic zirconia also. Different wavelengths were used to discriminate the Raman signal from fluorescence of the rare‐earth elements. Fourteen out of the 24 Raman active perovskite modes were identified. Mode symmetry is proposed for 12 of them, based on the polarization of the light backscattered by a rotated sample. Twenty‐one out of 25 Raman active modes of the garnet were listed and assigned by straight comparison with those of the parent compounds. Copyright © 2009 John Wiley & Sons, Ltd.
GdAlO3 perovskite and Er3Al5O12 garnet were studied by Raman microscopy in eutectic composites. Twelve GdAlO3 mode symmetries were proposed based on the backscattering from a rotated sample. Twenty‐one out of the 25 Raman active modes of Er3Al5O12 were assigned by comparison with those of the parent compounds.</description><subject>alumina</subject><subject>Backscattering</subject><subject>Chemical Sciences</subject><subject>Eutectics</subject><subject>garnet</subject><subject>Garnets</subject><subject>Material chemistry</subject><subject>Oxides</subject><subject>perovskite</subject><subject>Perovskites</subject><subject>polarization</subject><subject>Rare earth metals</subject><subject>Wavelengths</subject><subject>Zirconium dioxide</subject><issn>0377-0486</issn><issn>1097-4555</issn><issn>1097-4555</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNpF0dtO3DAQBmALUakLrdRH8CWVGupDHK8vIwRL6apB9CRxY83aDhi88dZOgOUt-sZNtIhejTT_p7mYH6EPlBxTQtjnu5SPmWB8D80oUbIohRD7aEa4lAUp59VbdJDzHSFEqYrO0N_LGCD5Z2fx2psUiytYQ4dzP9gtji2uA2t4sYI8AuuTM72PHYSwxTkGb33rxyA-eeuwG_opNhmb2PXgO9_d4IWtQ8PxxqX4kO997z7h08TrIBrK8A2kzvUYOovNsPIGX6eGvUNvWgjZvX-Zh-jn2emPk_Ni2Sy-nNTL4paxOS84IVIpZsAqR01ruTQcrKuYXa2IAHDWlSDmhllatdK2ajS0rcZvSDtGhh-ij7u7txD0Jvk1pK2O4PV5vdTTjjDFWVlWD3S0Rzu7SfHP4HKv1z4bFwJ0Lg5Z00pSxhWRfKTFjj764LavhynRUz16rEdP9eiLq-_T_O997t3Tq4d0ryvJpdC_vy30V3VdistfXJ_xfxwglMw</recordid><startdate>201009</startdate><enddate>201009</enddate><creator>Gouadec, G.</creator><creator>Makaoui, K.</creator><creator>Perrière, L.</creator><creator>Colomban, Ph</creator><creator>Mazerolles, L.</creator><general>John Wiley & Sons, Ltd</general><general>Wiley</general><scope>BSCLL</scope><scope>7QF</scope><scope>7QQ</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-8635-5069</orcidid><orcidid>https://orcid.org/0000-0001-6099-5423</orcidid><orcidid>https://orcid.org/0000-0003-3084-2383</orcidid><orcidid>https://orcid.org/0000-0002-1476-2765</orcidid></search><sort><creationdate>201009</creationdate><title>Polarized micro-Raman study of Al2O3-based directionally solidified oxide eutectics containing GdAlO3 perovskite, Er3Al5O12 garnet and cubic ZrO2</title><author>Gouadec, G. ; Makaoui, K. ; Perrière, L. ; Colomban, Ph ; Mazerolles, L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-h2283-3007992cad9e1cfd37c3ade62dbb05aaede4a58c2d16f7df9cfd1f65557dde4c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>alumina</topic><topic>Backscattering</topic><topic>Chemical Sciences</topic><topic>Eutectics</topic><topic>garnet</topic><topic>Garnets</topic><topic>Material chemistry</topic><topic>Oxides</topic><topic>perovskite</topic><topic>Perovskites</topic><topic>polarization</topic><topic>Rare earth metals</topic><topic>Wavelengths</topic><topic>Zirconium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gouadec, G.</creatorcontrib><creatorcontrib>Makaoui, K.</creatorcontrib><creatorcontrib>Perrière, L.</creatorcontrib><creatorcontrib>Colomban, Ph</creatorcontrib><creatorcontrib>Mazerolles, L.</creatorcontrib><collection>Istex</collection><collection>Aluminium Industry Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of Raman spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gouadec, G.</au><au>Makaoui, K.</au><au>Perrière, L.</au><au>Colomban, Ph</au><au>Mazerolles, L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Polarized micro-Raman study of Al2O3-based directionally solidified oxide eutectics containing GdAlO3 perovskite, Er3Al5O12 garnet and cubic ZrO2</atitle><jtitle>Journal of Raman spectroscopy</jtitle><addtitle>J. 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GdAlO3 perovskite and Er3Al5O12 garnet were studied by Raman microscopy in eutectic composites. Twelve GdAlO3 mode symmetries were proposed based on the backscattering from a rotated sample. Twenty‐one out of the 25 Raman active modes of Er3Al5O12 were assigned by comparison with those of the parent compounds.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/jrs.2523</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-8635-5069</orcidid><orcidid>https://orcid.org/0000-0001-6099-5423</orcidid><orcidid>https://orcid.org/0000-0003-3084-2383</orcidid><orcidid>https://orcid.org/0000-0002-1476-2765</orcidid></addata></record> |
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subjects | alumina Backscattering Chemical Sciences Eutectics garnet Garnets Material chemistry Oxides perovskite Perovskites polarization Rare earth metals Wavelengths Zirconium dioxide |
title | Polarized micro-Raman study of Al2O3-based directionally solidified oxide eutectics containing GdAlO3 perovskite, Er3Al5O12 garnet and cubic ZrO2 |
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