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Platinum nanoparticles embedded into polyaniline on carbon cloth: improvement of oxygen reduction at cathode of microbial fuel cell used for conversion of medicinal plant wastes into bio-energy
A microbial fuel cell is a biological electrochemical system that extracts electrons stored in organic matter by oxidation using catalytic properties of microorganisms at bioanode. The major problem in such device, is however limited power production due to slow kinetic of oxygen reduction at cathod...
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| Published in: | Environmental technology 2022-04, Vol.43 (9), p.1359-1369 |
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| creator | Zerrouki, Aicha Kameche, Mostefa Ait Amer, Ahcene Tayeb, Ahlem Moussaoui, Douniazeed Innocent, Christophe |
| description | A microbial fuel cell is a biological electrochemical system that extracts electrons stored in organic matter by oxidation using catalytic properties of microorganisms at bioanode. The major problem in such device, is however limited power production due to slow kinetic of oxygen reduction at cathode. It is worthwhile to develop new materials that fulfil these requirements. The polymerization of aniline onto carbon cloth for effective electrodeposition of platinum nanoparticles has been carried out by chronoamperometry and cyclic voltammetry. Three materials were thus elaborated, namely pristine carbon cloth, carbon cloth modified with platinum and carbon cloth modified by polymerization of aniline for immobilization of Pt-nanoparticles. The FTIR spectroscopy analysis revealed characteristic band located in 1720-1650 cm
−1
, attributed to imine function, main component in skeleton of polymer PANI chain. The modified materials have been utilized as cathode in cell inoculated with medicinal plant wastes for improvement of oxygen reduction. Modified cathode with CC-PANI-Pt proved higher performances in all respects: increase of cell voltage from 338 to 765 mV and power density from 862 to 1510 mW/m
2
and abatement of COD of microbial inoculum leachate to 88%. Another feature of cell with modified cathode CC-PANI-Pt, was the enormous electric charge density harvested upon oxidation of 1 mL of acetate 7.62 C/cm
2
compared to that of cell with pristine CC cathode 0.54 C/cm
2
. Nevertheless, coulombic efficiency for conversion of medicinal plant wastes into bioenergy was relatively lower 9%, making in evidence that elaborated electrochemical device was rather efficient and benificial environmentally than energetically. |
| doi_str_mv | 10.1080/09593330.2020.1829088 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_02967022v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2446669470</sourcerecordid><originalsourceid>FETCH-LOGICAL-c428t-2b51d6bd43329d821630e3d9b772e7d38c6af192a9bb80ec53284c25c4744b943</originalsourceid><addsrcrecordid>eNp9ks1u1DAUhSMEotPCI4AssYFFiuM4ic2qVQUUaSRYgMTOcuybjivHHmxnyjweb1abmXbBgtWVrr9z_3yq6lWDzxvM8HvMO962LT4nmOQUIxwz9qRaNXTgNWXDz6fVqjB1gU6q0xhvMSasY_x5ddISPnSUd6vqzzcrk3HLjJx0fitDMspCRDCPoDVoZFzyaOvtXjpjjQPkHVIyjCVYnzYfkJm3we9gBpeQn5D_vb8BhwLoRSWTMZmyIG28hvI8GxX8aKRF0wIWKbAWLTE3mnxAyrsdhFhUBQVtlHEZ3VqZi9_JmPJofycaja_BQbjZv6ieTdJGeHmMZ9WPTx-_X13X66-fv1xdrmtFCUs1GbtG96OmbV5eM9L0LYZW83EYCAy6ZaqXU8OJ5OPIMKiuJYwq0ik6UDpy2p5V7w51N9KKbTCzDHvhpRHXl2tRcpjwfsCE7JrMvj2w-TK_FohJzCaWVaUDv0RBKO37ntMBZ_TNP-itX0JeOlM97SjpGS7NuwOVjxdjgOlxggaL4gfx4AdR_CCOfsi618fqy5jP-ah6MEAGLg6AcfkDZnnng9Uiyb31YQrSKRNF-_8e91wnx6A</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2645426804</pqid></control><display><type>article</type><title>Platinum nanoparticles embedded into polyaniline on carbon cloth: improvement of oxygen reduction at cathode of microbial fuel cell used for conversion of medicinal plant wastes into bio-energy</title><source>Taylor and Francis Science and Technology Collection</source><creator>Zerrouki, Aicha ; Kameche, Mostefa ; Ait Amer, Ahcene ; Tayeb, Ahlem ; Moussaoui, Douniazeed ; Innocent, Christophe</creator><creatorcontrib>Zerrouki, Aicha ; Kameche, Mostefa ; Ait Amer, Ahcene ; Tayeb, Ahlem ; Moussaoui, Douniazeed ; Innocent, Christophe</creatorcontrib><description>A microbial fuel cell is a biological electrochemical system that extracts electrons stored in organic matter by oxidation using catalytic properties of microorganisms at bioanode. The major problem in such device, is however limited power production due to slow kinetic of oxygen reduction at cathode. It is worthwhile to develop new materials that fulfil these requirements. The polymerization of aniline onto carbon cloth for effective electrodeposition of platinum nanoparticles has been carried out by chronoamperometry and cyclic voltammetry. Three materials were thus elaborated, namely pristine carbon cloth, carbon cloth modified with platinum and carbon cloth modified by polymerization of aniline for immobilization of Pt-nanoparticles. The FTIR spectroscopy analysis revealed characteristic band located in 1720-1650 cm
−1
, attributed to imine function, main component in skeleton of polymer PANI chain. The modified materials have been utilized as cathode in cell inoculated with medicinal plant wastes for improvement of oxygen reduction. Modified cathode with CC-PANI-Pt proved higher performances in all respects: increase of cell voltage from 338 to 765 mV and power density from 862 to 1510 mW/m
2
and abatement of COD of microbial inoculum leachate to 88%. Another feature of cell with modified cathode CC-PANI-Pt, was the enormous electric charge density harvested upon oxidation of 1 mL of acetate 7.62 C/cm
2
compared to that of cell with pristine CC cathode 0.54 C/cm
2
. Nevertheless, coulombic efficiency for conversion of medicinal plant wastes into bioenergy was relatively lower 9%, making in evidence that elaborated electrochemical device was rather efficient and benificial environmentally than energetically.</description><identifier>ISSN: 0959-3330</identifier><identifier>EISSN: 1479-487X</identifier><identifier>DOI: 10.1080/09593330.2020.1829088</identifier><identifier>PMID: 32975495</identifier><language>eng</language><publisher>England: Taylor & Francis</publisher><subject>Acetic acid ; Aniline ; Aniline Compounds - chemistry ; Bacterial leaching ; Biochemical fuel cells ; Bioelectric Energy Sources ; Carbon ; Carbon - chemistry ; Cathodes ; Charge density ; Chemical oxygen demand ; Chemical Sciences ; Cloth ; Conversion ; electroactive biofilm ; Electrochemistry ; Electrodes ; Fuel cells ; Fuel technology ; Herbal medicine ; Immobilization ; Inoculum ; Leachates ; medicinal plant wastes treatment ; Medicinal plants ; Metal Nanoparticles ; microbial fuel cell conception ; Microorganisms ; Nanoparticles ; Organic matter ; Oxidation ; Oxygen ; Oxygen - chemistry ; oxygen reduction ; Plants, Medicinal ; Platinum ; platinum immobilization ; Polyanilines ; Polymerization ; Polymers ; Reduction ; Renewable energy ; Wastes</subject><ispartof>Environmental technology, 2022-04, Vol.43 (9), p.1359-1369</ispartof><rights>2020 Informa UK Limited, trading as Taylor & Francis Group 2020</rights><rights>2020 Informa UK Limited, trading as Taylor & Francis Group</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c428t-2b51d6bd43329d821630e3d9b772e7d38c6af192a9bb80ec53284c25c4744b943</citedby><cites>FETCH-LOGICAL-c428t-2b51d6bd43329d821630e3d9b772e7d38c6af192a9bb80ec53284c25c4744b943</cites><orcidid>0000-0001-5362-9791</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,27903,27904</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/32975495$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-02967022$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Zerrouki, Aicha</creatorcontrib><creatorcontrib>Kameche, Mostefa</creatorcontrib><creatorcontrib>Ait Amer, Ahcene</creatorcontrib><creatorcontrib>Tayeb, Ahlem</creatorcontrib><creatorcontrib>Moussaoui, Douniazeed</creatorcontrib><creatorcontrib>Innocent, Christophe</creatorcontrib><title>Platinum nanoparticles embedded into polyaniline on carbon cloth: improvement of oxygen reduction at cathode of microbial fuel cell used for conversion of medicinal plant wastes into bio-energy</title><title>Environmental technology</title><addtitle>Environ Technol</addtitle><description>A microbial fuel cell is a biological electrochemical system that extracts electrons stored in organic matter by oxidation using catalytic properties of microorganisms at bioanode. The major problem in such device, is however limited power production due to slow kinetic of oxygen reduction at cathode. It is worthwhile to develop new materials that fulfil these requirements. The polymerization of aniline onto carbon cloth for effective electrodeposition of platinum nanoparticles has been carried out by chronoamperometry and cyclic voltammetry. Three materials were thus elaborated, namely pristine carbon cloth, carbon cloth modified with platinum and carbon cloth modified by polymerization of aniline for immobilization of Pt-nanoparticles. The FTIR spectroscopy analysis revealed characteristic band located in 1720-1650 cm
−1
, attributed to imine function, main component in skeleton of polymer PANI chain. The modified materials have been utilized as cathode in cell inoculated with medicinal plant wastes for improvement of oxygen reduction. Modified cathode with CC-PANI-Pt proved higher performances in all respects: increase of cell voltage from 338 to 765 mV and power density from 862 to 1510 mW/m
2
and abatement of COD of microbial inoculum leachate to 88%. Another feature of cell with modified cathode CC-PANI-Pt, was the enormous electric charge density harvested upon oxidation of 1 mL of acetate 7.62 C/cm
2
compared to that of cell with pristine CC cathode 0.54 C/cm
2
. Nevertheless, coulombic efficiency for conversion of medicinal plant wastes into bioenergy was relatively lower 9%, making in evidence that elaborated electrochemical device was rather efficient and benificial environmentally than energetically.</description><subject>Acetic acid</subject><subject>Aniline</subject><subject>Aniline Compounds - chemistry</subject><subject>Bacterial leaching</subject><subject>Biochemical fuel cells</subject><subject>Bioelectric Energy Sources</subject><subject>Carbon</subject><subject>Carbon - chemistry</subject><subject>Cathodes</subject><subject>Charge density</subject><subject>Chemical oxygen demand</subject><subject>Chemical Sciences</subject><subject>Cloth</subject><subject>Conversion</subject><subject>electroactive biofilm</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Fuel cells</subject><subject>Fuel technology</subject><subject>Herbal medicine</subject><subject>Immobilization</subject><subject>Inoculum</subject><subject>Leachates</subject><subject>medicinal plant wastes treatment</subject><subject>Medicinal plants</subject><subject>Metal Nanoparticles</subject><subject>microbial fuel cell conception</subject><subject>Microorganisms</subject><subject>Nanoparticles</subject><subject>Organic matter</subject><subject>Oxidation</subject><subject>Oxygen</subject><subject>Oxygen - chemistry</subject><subject>oxygen reduction</subject><subject>Plants, Medicinal</subject><subject>Platinum</subject><subject>platinum immobilization</subject><subject>Polyanilines</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Reduction</subject><subject>Renewable energy</subject><subject>Wastes</subject><issn>0959-3330</issn><issn>1479-487X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9ks1u1DAUhSMEotPCI4AssYFFiuM4ic2qVQUUaSRYgMTOcuybjivHHmxnyjweb1abmXbBgtWVrr9z_3yq6lWDzxvM8HvMO962LT4nmOQUIxwz9qRaNXTgNWXDz6fVqjB1gU6q0xhvMSasY_x5ddISPnSUd6vqzzcrk3HLjJx0fitDMspCRDCPoDVoZFzyaOvtXjpjjQPkHVIyjCVYnzYfkJm3we9gBpeQn5D_vb8BhwLoRSWTMZmyIG28hvI8GxX8aKRF0wIWKbAWLTE3mnxAyrsdhFhUBQVtlHEZ3VqZi9_JmPJofycaja_BQbjZv6ieTdJGeHmMZ9WPTx-_X13X66-fv1xdrmtFCUs1GbtG96OmbV5eM9L0LYZW83EYCAy6ZaqXU8OJ5OPIMKiuJYwq0ik6UDpy2p5V7w51N9KKbTCzDHvhpRHXl2tRcpjwfsCE7JrMvj2w-TK_FohJzCaWVaUDv0RBKO37ntMBZ_TNP-itX0JeOlM97SjpGS7NuwOVjxdjgOlxggaL4gfx4AdR_CCOfsi618fqy5jP-ah6MEAGLg6AcfkDZnnng9Uiyb31YQrSKRNF-_8e91wnx6A</recordid><startdate>20220416</startdate><enddate>20220416</enddate><creator>Zerrouki, Aicha</creator><creator>Kameche, Mostefa</creator><creator>Ait Amer, Ahcene</creator><creator>Tayeb, Ahlem</creator><creator>Moussaoui, Douniazeed</creator><creator>Innocent, Christophe</creator><general>Taylor & Francis</general><general>Taylor & Francis Ltd</general><general>Taylor & Francis: STM, Behavioural Science and Public Health Titles</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QL</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SN</scope><scope>7SP</scope><scope>7SR</scope><scope>7ST</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>7U7</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>M7N</scope><scope>P64</scope><scope>SOI</scope><scope>7X8</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0001-5362-9791</orcidid></search><sort><creationdate>20220416</creationdate><title>Platinum nanoparticles embedded into polyaniline on carbon cloth: improvement of oxygen reduction at cathode of microbial fuel cell used for conversion of medicinal plant wastes into bio-energy</title><author>Zerrouki, Aicha ; Kameche, Mostefa ; Ait Amer, Ahcene ; Tayeb, Ahlem ; Moussaoui, Douniazeed ; Innocent, Christophe</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c428t-2b51d6bd43329d821630e3d9b772e7d38c6af192a9bb80ec53284c25c4744b943</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Acetic acid</topic><topic>Aniline</topic><topic>Aniline Compounds - chemistry</topic><topic>Bacterial leaching</topic><topic>Biochemical fuel cells</topic><topic>Bioelectric Energy Sources</topic><topic>Carbon</topic><topic>Carbon - chemistry</topic><topic>Cathodes</topic><topic>Charge density</topic><topic>Chemical oxygen demand</topic><topic>Chemical Sciences</topic><topic>Cloth</topic><topic>Conversion</topic><topic>electroactive biofilm</topic><topic>Electrochemistry</topic><topic>Electrodes</topic><topic>Fuel cells</topic><topic>Fuel technology</topic><topic>Herbal medicine</topic><topic>Immobilization</topic><topic>Inoculum</topic><topic>Leachates</topic><topic>medicinal plant wastes treatment</topic><topic>Medicinal plants</topic><topic>Metal Nanoparticles</topic><topic>microbial fuel cell conception</topic><topic>Microorganisms</topic><topic>Nanoparticles</topic><topic>Organic matter</topic><topic>Oxidation</topic><topic>Oxygen</topic><topic>Oxygen - chemistry</topic><topic>oxygen reduction</topic><topic>Plants, Medicinal</topic><topic>Platinum</topic><topic>platinum immobilization</topic><topic>Polyanilines</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Reduction</topic><topic>Renewable energy</topic><topic>Wastes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zerrouki, Aicha</creatorcontrib><creatorcontrib>Kameche, Mostefa</creatorcontrib><creatorcontrib>Ait Amer, Ahcene</creatorcontrib><creatorcontrib>Tayeb, Ahlem</creatorcontrib><creatorcontrib>Moussaoui, Douniazeed</creatorcontrib><creatorcontrib>Innocent, Christophe</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Ecology Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Toxicology Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environment Abstracts</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Environmental technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zerrouki, Aicha</au><au>Kameche, Mostefa</au><au>Ait Amer, Ahcene</au><au>Tayeb, Ahlem</au><au>Moussaoui, Douniazeed</au><au>Innocent, Christophe</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Platinum nanoparticles embedded into polyaniline on carbon cloth: improvement of oxygen reduction at cathode of microbial fuel cell used for conversion of medicinal plant wastes into bio-energy</atitle><jtitle>Environmental technology</jtitle><addtitle>Environ Technol</addtitle><date>2022-04-16</date><risdate>2022</risdate><volume>43</volume><issue>9</issue><spage>1359</spage><epage>1369</epage><pages>1359-1369</pages><issn>0959-3330</issn><eissn>1479-487X</eissn><abstract>A microbial fuel cell is a biological electrochemical system that extracts electrons stored in organic matter by oxidation using catalytic properties of microorganisms at bioanode. The major problem in such device, is however limited power production due to slow kinetic of oxygen reduction at cathode. It is worthwhile to develop new materials that fulfil these requirements. The polymerization of aniline onto carbon cloth for effective electrodeposition of platinum nanoparticles has been carried out by chronoamperometry and cyclic voltammetry. Three materials were thus elaborated, namely pristine carbon cloth, carbon cloth modified with platinum and carbon cloth modified by polymerization of aniline for immobilization of Pt-nanoparticles. The FTIR spectroscopy analysis revealed characteristic band located in 1720-1650 cm
−1
, attributed to imine function, main component in skeleton of polymer PANI chain. The modified materials have been utilized as cathode in cell inoculated with medicinal plant wastes for improvement of oxygen reduction. Modified cathode with CC-PANI-Pt proved higher performances in all respects: increase of cell voltage from 338 to 765 mV and power density from 862 to 1510 mW/m
2
and abatement of COD of microbial inoculum leachate to 88%. Another feature of cell with modified cathode CC-PANI-Pt, was the enormous electric charge density harvested upon oxidation of 1 mL of acetate 7.62 C/cm
2
compared to that of cell with pristine CC cathode 0.54 C/cm
2
. Nevertheless, coulombic efficiency for conversion of medicinal plant wastes into bioenergy was relatively lower 9%, making in evidence that elaborated electrochemical device was rather efficient and benificial environmentally than energetically.</abstract><cop>England</cop><pub>Taylor & Francis</pub><pmid>32975495</pmid><doi>10.1080/09593330.2020.1829088</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0001-5362-9791</orcidid></addata></record> |
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| ispartof | Environmental technology, 2022-04, Vol.43 (9), p.1359-1369 |
| issn | 0959-3330 1479-487X |
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| source | Taylor and Francis Science and Technology Collection |
| subjects | Acetic acid Aniline Aniline Compounds - chemistry Bacterial leaching Biochemical fuel cells Bioelectric Energy Sources Carbon Carbon - chemistry Cathodes Charge density Chemical oxygen demand Chemical Sciences Cloth Conversion electroactive biofilm Electrochemistry Electrodes Fuel cells Fuel technology Herbal medicine Immobilization Inoculum Leachates medicinal plant wastes treatment Medicinal plants Metal Nanoparticles microbial fuel cell conception Microorganisms Nanoparticles Organic matter Oxidation Oxygen Oxygen - chemistry oxygen reduction Plants, Medicinal Platinum platinum immobilization Polyanilines Polymerization Polymers Reduction Renewable energy Wastes |
| title | Platinum nanoparticles embedded into polyaniline on carbon cloth: improvement of oxygen reduction at cathode of microbial fuel cell used for conversion of medicinal plant wastes into bio-energy |
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