Tristhienylphenylamine--extended dithiafulvene hybrids as bifunctional electroactive species

Extended hybrid conjugated systems based on a trithienylphenylamine core with 1, 2 and 3 peripheral dithiafulvenyl units have been synthesized and studied by cyclic voltammetry and UV-Vis. absorption spectroscopy. Theoretical calculations have also been undergone. The behaviour of these derivatives...

Full description

Saved in:
Bibliographic Details
Published in:Organic & biomolecular chemistry 2011-02, Vol.9 (4), p.1034-1040
Main Authors: Ripaud, Emilie, Leriche, Philippe, Cocherel, Nicolas, Cauchy, Thomas, Frère, Pierre, Roncali, Jean
Format: Article
Language:English
Subjects:
Chemical Sciences
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Extended hybrid conjugated systems based on a trithienylphenylamine core with 1, 2 and 3 peripheral dithiafulvenyl units have been synthesized and studied by cyclic voltammetry and UV-Vis. absorption spectroscopy. Theoretical calculations have also been undergone. The behaviour of these derivatives which depends on the number of dithiafulvene moieties grafted of the central core is cleared up. One polymer, obtained from derivative 3 presents polyelectrochromic properties.
ISSN:1477-0520
1477-0539
DOI:10.1039/c0ob00471e