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Stereospecific emulsion polymerization of 2-phenyl-1,3-butadiene
In order to adapt the reduction-activation reaction of hydrogen peroxide to the polymerization of 2-phenyl-1,3-butadiene, emulsion polymerization was carried out with H 2O 2/Fe 2+ as catalyst in the presence of sodium pyrophosphate. The influences of emulsifier, iron ligand, electrolyte salt and pol...
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| Published in: | European polymer journal 1991, Vol.27 (8), p.747-749 |
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| Main Authors: | , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c368t-d10a152561bea7ac81d69bb741b10a4bf396333de5dd865e82724e3c489bb3423 |
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| cites | cdi_FETCH-LOGICAL-c368t-d10a152561bea7ac81d69bb741b10a4bf396333de5dd865e82724e3c489bb3423 |
| container_end_page | 749 |
| container_issue | 8 |
| container_start_page | 747 |
| container_title | European polymer journal |
| container_volume | 27 |
| creator | Friedmann, Gilbert Brosse, Nicolas |
| description | In order to adapt the reduction-activation reaction of hydrogen peroxide to the polymerization of 2-phenyl-1,3-butadiene, emulsion polymerization was carried out with H
2O
2/Fe
2+ as catalyst in the presence of sodium pyrophosphate. The influences of emulsifier, iron ligand, electrolyte salt and polymerization temperature on the microstructure of the resulting polymer have been studied. It is possible to achieve a 100%
cis-1,4 stereoregular structure. |
| doi_str_mv | 10.1016/0014-3057(91)90002-6 |
| format | article |
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2O
2/Fe
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2O
2/Fe
2+ as catalyst in the presence of sodium pyrophosphate. The influences of emulsifier, iron ligand, electrolyte salt and polymerization temperature on the microstructure of the resulting polymer have been studied. It is possible to achieve a 100%
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2O
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| fulltext | fulltext |
| identifier | ISSN: 0014-3057 |
| ispartof | European polymer journal, 1991, Vol.27 (8), p.747-749 |
| issn | 0014-3057 1873-1945 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_03151477v1 |
| source | Backfile Package - Materials Science [YMS] |
| subjects | Applied sciences Chemical and Process Engineering Chemical Sciences Engineering Sciences Exact sciences and technology Materials Organic chemistry Organic polymers Physicochemistry of polymers Polymerization Polymers Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Stereospecific emulsion polymerization of 2-phenyl-1,3-butadiene |
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