On the spontaneous carboxylation of 1-butyl-3-methylimidazolium acetate by carbon dioxide

The formation of 1-butyl-3-methylimidazolium-2-carboxylate in the mixture of CO(2) with 1-butyl-3-methylimidazolium acetate under mild conditions (298 K, 0.1 MPa) has been put in evidence in the liquid phase using Raman and infrared spectroscopy complemented by DFT calculations and NMR ((1)H, (13)C,...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (9), p.1245-1247
Main Authors: Besnard, Marcel, Cabaço, M Isabel, Chávez, Fabián Vaca, Pinaud, Noël, Sebastião, Pedro J, Coutinho, João A P, Danten, Yann
Format: Article
Language:English
Subjects:
Acetates
Carbon dioxide
Carboxylation
Chemical Sciences
Environmental Sciences
Infrared spectroscopy
Liquid phases
Mathematical analysis
Physics
Spectroscopy
Spontaneous
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The formation of 1-butyl-3-methylimidazolium-2-carboxylate in the mixture of CO(2) with 1-butyl-3-methylimidazolium acetate under mild conditions (298 K, 0.1 MPa) has been put in evidence in the liquid phase using Raman and infrared spectroscopy complemented by DFT calculations and NMR ((1)H, (13)C, (15)N) spectroscopy.
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc16702b