Effects of curing cycles on developing strength and microstructure of goethite-rich aluminosilicate (corroded laterite) based geopolymer composites

• Published in: Materials chemistry and physics 2021-09, Vol.270, p.124864, Article 124864
• Main Authors: Nouping Fekoua, Joelle Nadia, Kaze, Cyriaque Rodrigue, Duna, Linda Lekuna, Ghazouni, Armeni, Ndassa, Ibrahim Mbouombuo, Kamseu, Elie, Rossignol, Sylvie, Leonelli, Cristina
• Format: Article
• Language: English
• Subjects: Aluminosilicates; Aluminum silicates; Ashes; Bulk density; Chemical Sciences; Composite materials; Curing cycles; Engineering Sciences; Geopolymers; Humidity; Laterite; Laterites; Material chemistry; Materials; Mechanical properties; Mechanical tests; Microstructure; Physical properties; Porosity; Quarry sand dust; Rice husk ash; Room temperature; Steam curing
• ISSN: 0254-0584; 1879-3312
• DOI: 10.1016/j.matchemphys.2021.124864

The present work carried out the influence of curing cycles on the performance of laterite-based geopolymer composites. To do so, the end products were obtained by altering laterite with 15, 20, and 25 wt% of rice husk ash (RHA). Alkaline solution in a constant solid/liquid ratio of 0.35 was added together with fine and coarse aggregates (representing equal and double weight of laterite, respectively). The different obtained matrices were treated in the following three curing cycles before characterization: room temperature curing (RTC), oven curing at 80 °C (OTC) and controlled humidity steam curing at 80 °C (STC). The mechanical tests carried out at 28 days give the following maximum values for each curing mode: 16.40, 28.82 and 56.41 MPa for RTC, OTC, and STC modes respectively. This means that when the samples, submitted in a moisture-controlled environment, the end products are more stable, less porous and resistant. Regarding the physical properties, the results show that the maximum value of open porosity is 11.62% corresponding to a matrix that was cured at room temperature without rice husk ash added, while the minimum value of 7% corresponds to a matrix that was cured under controlled humidity and containing 20% rice husk ash. The optimum and minimum absorption values are 2.70 and 4.60% respectively for the OTC and RTC curing modes. As for bulk densities, the optimum value is 2.64 g cm−3 for the matrix having 15% rice husk ash and the minimum value is 2.33 g cm−3 for a matrix having 20% rice husk ash, for OTC and STC curing modes respectively. The appropriate curing type for laterite-based geopolymer is when the humidity is controlled. •Laterite, aggregates and rice husk ash were used to produce geopolymer composites.•Geopolymer composites were cured at Room curing temperature (RTC), Oven curing and Steam curing (STC).•Applying the steam curing (STC) under controlled humidity (>65%) optimized the geopolymerization reaction.•High mechanical (56.41 MPa) was achieved on sample containing 25 wt% of RHA.•This sample also exhibits compact and dense structure with few accessible voids.