Monomeric (dialkylamino)boranes: a new and efficient boron source in palladium catalyzed C-B bond formation with aryl halides

Thermal decomposition of hindered amine-borane adducts leads in high yields to monomeric (dialkylamino)boranes R1R2N-BH2 (R1 and R2 = alkyl) that are new and efficient boron-sources in the Pd0 catalyzed borylation reaction affording monomeric aryl(dialkylamino)boranes R1R2N-BHR3 (R3 = aryl).

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2003-09 (18), p.2280-2281
Main Authors: Euzenat, Lisenn, Horhant, David, Ribourdouille, Yann, Duriez, Christophe, Alcaraz, Gilles, Vaultier, Michel
Format: Article
Language:English
Subjects:
Chemical Sciences
Organic chemistry
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Summary:Thermal decomposition of hindered amine-borane adducts leads in high yields to monomeric (dialkylamino)boranes R1R2N-BH2 (R1 and R2 = alkyl) that are new and efficient boron-sources in the Pd0 catalyzed borylation reaction affording monomeric aryl(dialkylamino)boranes R1R2N-BHR3 (R3 = aryl).
ISSN:1359-7345
1364-548X
DOI:10.1039/b306874a