Laser induced breakdown in gas mixtures. Experimental and statistical investigation on n-decane ignition: Pressure, mixture composition and equivalence ratio effects

• Published in: Journal of hazardous materials 2020-04, Vol.388, p.119266-119266, Article 119266
• Main Authors: Mokrani, Nabil, Gillard, Philippe
• Format: Article
• Language: English
• Subjects: Breakdown; Chemical Sciences; Laser-ignition; MIE; N-Decane; Stochastic study
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2018.03.046

•A new full study on laser ignition of decane in air.•Accurate measurement of the MIE for decane in air.•Quantitative results with both incident and absorbed energy.•Relationship between incident and absorbed energy under various conditions.•Influence of parameters (pressure, equivalence ratio, purity) on ignition conditions. This paper presents a physical and statistical approach to laser-induced breakdown in n-decane/N2 + O2 mixtures as a function of incident or absorbed energy. A parametric study, with pressure, fuel purity and equivalence ratio, was conducted to determine the incident and absorbed energies involved in producing breakdown, followed or not by ignition. The experiments were performed using a Q-switched Nd-YAG laser (1064 nm) inside a cylindrical 1-l combustion chamber in the range of 1–100 mJ of incident energy. A stochastic study of breakdown and ignition probabilities showed that the mixture composition had a significant effect on ignition with large variation of incident or absorbed energy required to obtain 50% of breakdown. It was observed that the combustion products absorb more energy coming from the laser. The effect of pressure on the ignition probabilities of lean and near stoichiometric mixtures was also investigated. It was found that a high ignition energy E50% is required for lean mixtures at high pressures (3 bar). The present study provides new data obtained on an original experimental setup and the results, close to laboratory-produced laser ignition phenomena, will enhance the understanding of initial conditions on the breakdown or ignition probabilities for different mixtures.