Glass-forming ability and ZrO2 saturation limits in the magnesium aluminosilicate system

Containerless melting was employed to evaluate the influence of increasing ZrO2 additions on the glass-forming ability of peraluminous melts in the magnesium aluminosilicate system. The saturation limit of this oxide in glasses along the silica-cordierite join (SiO2–Mg2Al4Si5O18) is inversely propor...

Full description

Saved in:
Bibliographic Details
Published in:Ceramics international 2022-03, Vol.48 (6), p.8433-8439
Main Authors: Zandonà, Alessio, Moustrous, Marine, Genevois, Cécile, Véron, Emmanuel, Canizarès, Aurélien, Allix, Mathieu
Format: Article
Language:English
Subjects:
Chemical Sciences
Containerless melting
Cristallography
Glass solubility
Glass-forming ability
Inorganic chemistry
Material chemistry
Phase separation
ZrO2 nucleation
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Containerless melting was employed to evaluate the influence of increasing ZrO2 additions on the glass-forming ability of peraluminous melts in the magnesium aluminosilicate system. The saturation limit of this oxide in glasses along the silica-cordierite join (SiO2–Mg2Al4Si5O18) is inversely proportional to the SiO2 content; however, a limited solubility of ZrO2 in melt-quenched silica exists (∼2 mol%). Peraluminous samples (particularly MgO-free samples) exhibited a substantially higher capability of incorporating ZrO2 without undergoing devitrification during cooling. TEM investigations revealed phase separation in all amorphous samples off the MgO = Al2O3 line, with ZrO2 preferentially segregating into a SiO2-depleted phase. These results identify the key role of Al2O3 for the structural incorporation of ZrO2 in silicate melts, opening up alternative pathways for the development of glasses and glass-ceramics respectively based on the homogeneous distribution of ZrO2 or, in turn, on its exploitation to induce phase separation and crystal nucleation.
ISSN:0272-8842
1873-3956
DOI:10.1016/j.ceramint.2021.12.051