High temperature carbon–carbon supercapacitor using ionic liquid as electrolyte

This paper presents results about the electrochemical and cycling characterizations of a supercapacitor cell using a microporous activated carbon as the active material and N-butyl- N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PYR 14TFSI) ionic liquid as the electrolyte. The microporous...

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Published in:Journal of power sources 2007-03, Vol.165 (2), p.922-927
Main Authors: Balducci, A., Dugas, R., Taberna, P.L., Simon, P., Plée, D., Mastragostino, M., Passerini, S.
Format: Article
Language:English
Subjects:
Activated carbon
Applied sciences
Capacitors. Resistors. Filters
Chemical Sciences
Electrical engineering. Electrical power engineering
Exact sciences and technology
Ionic liquids
Material chemistry
Microporous carbon
Supercapacitor
Various equipment and components
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cited_by cdi_FETCH-LOGICAL-c521t-d3ef936a88f12af0c3589f20304720d3c668df015b73d2fd3ac0567908cbe7b03
cites cdi_FETCH-LOGICAL-c521t-d3ef936a88f12af0c3589f20304720d3c668df015b73d2fd3ac0567908cbe7b03
container_end_page 927
container_issue 2
container_start_page 922
container_title Journal of power sources
container_volume 165
creator Balducci, A.
Dugas, R.
Taberna, P.L.
Simon, P.
Plée, D.
Mastragostino, M.
Passerini, S.
description This paper presents results about the electrochemical and cycling characterizations of a supercapacitor cell using a microporous activated carbon as the active material and N-butyl- N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PYR 14TFSI) ionic liquid as the electrolyte. The microporous activated carbon exhibited a specific capacitance of 60 F g −1 measured from the three-electrode cyclic voltammetry experiments at 20 mV s −1 scan rate, with a maximum operating potential range of 4.5 V at 60 °C. A coin cell assembled with this microporous activated carbon and PYR 14TFSI as the electrolyte was cycled for 40,000 cycles without any change of cell resistance (9 Ω cm 2), at a voltage up to 3.5 V at 60 °C, demonstrating a high cycling stability as well as a high stable specific capacitance in this ionic liquid electrolyte. These high performances make now this type of supercapacitor suitable for high temperature applications (≥60 °C).
doi_str_mv 10.1016/j.jpowsour.2006.12.048
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The microporous activated carbon exhibited a specific capacitance of 60 F g −1 measured from the three-electrode cyclic voltammetry experiments at 20 mV s −1 scan rate, with a maximum operating potential range of 4.5 V at 60 °C. A coin cell assembled with this microporous activated carbon and PYR 14TFSI as the electrolyte was cycled for 40,000 cycles without any change of cell resistance (9 Ω cm 2), at a voltage up to 3.5 V at 60 °C, demonstrating a high cycling stability as well as a high stable specific capacitance in this ionic liquid electrolyte. These high performances make now this type of supercapacitor suitable for high temperature applications (≥60 °C).</description><identifier>ISSN: 0378-7753</identifier><identifier>EISSN: 1873-2755</identifier><identifier>DOI: 10.1016/j.jpowsour.2006.12.048</identifier><identifier>CODEN: JPSODZ</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Activated carbon ; Applied sciences ; Capacitors. 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subjects Activated carbon
Applied sciences
Capacitors. Resistors. Filters
Chemical Sciences
Electrical engineering. Electrical power engineering
Exact sciences and technology
Ionic liquids
Material chemistry
Microporous carbon
Supercapacitor
Various equipment and components
title High temperature carbon–carbon supercapacitor using ionic liquid as electrolyte
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