Kinetic, thermodynamic and mechanism study of the adsorption of phenol on Moroccan clay

Phenol is a toxic pollutant commonly found in industrial wastewaters. Thus, the objective of the present study consisted in removing this organic compound from aqueous solution using a clay from Morocco. Adsorbent characterization was performed using XRF, XRD, SEM, BET and FTIR techniques. Phenol ad...

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Bibliographic Details
Published in:Journal of molecular liquids 2020-08, Vol.312, p.113383, Article 113383
Main Authors: Dehmani, Younes, Sellaoui, Lotfi, Alghamdi, Youssef, Lainé, Juliette, Badawi, Michael, Amhoud, Abdellatif, Bonilla-Petriciolet, A., Lamhasni, Taibi, Abouarnadasse, Sadik
Format: Article
Language:English
Subjects:
Adsorption
Chemical Sciences
Clay
Phenol
Physics
Statistical physics model
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Summary:Phenol is a toxic pollutant commonly found in industrial wastewaters. Thus, the objective of the present study consisted in removing this organic compound from aqueous solution using a clay from Morocco. Adsorbent characterization was performed using XRF, XRD, SEM, BET and FTIR techniques. Phenol adsorption isotherms and kinetics were experimentally quantified and modeling studies were carried out by statistical physics to explain the phenol adsorption on raw and activated clays. Results showed that: i) the activation of the clay by sulfuric acid increased its adsorption capacity, ii) the phenol adsorption was well fitted by the pseudo-second-order kinetic and Langmuir isotherm models, iii) the adsorption mechanism was dominated by electrostatic interactions and was associated to a multi-docking process. To conclude, the present study illustrates the valorization of this Moroccan clay as a low-cost and effective adsorbent for phenol removal from wastewaters. •Clays were valorized as phenol adsorbents from aqueous solution.•Thermodynamics of phenol adsorption on clays was studied.•Phenol adsorption mechanism was analyzed via statistical physics modeling.
ISSN:0167-7322
1873-3166
DOI:10.1016/j.molliq.2020.113383