Intercepting a Transient Pyridine N-Oxide Fe(III) Species in Catalytic Oxygen Atom Transfer Reaction

An unprecedented pyridine- N -oxide Fe( iii ) intermediate has been detected as a potent oxidizing species for catalytic OAT reactions.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2021-11, Vol.57 (95), p.12836-12839
Main Authors: Vo, Nhat Tam, Herrero, Christian, Guillot, Régis, Inceoglu, Tanya, Leibl, Winfried, Clémancey, Martin, Dubourdeaux, Patrick, Blondin, Geneviève, Aukauloo, Ally, Sircoglou, Marie
Format: Article
Language:English
Subjects:
Catalysis
Chemical Sciences
Coordination chemistry
or physical chemistry
Theoretical and
Online Access:Get full text
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Description
Summary:An unprecedented pyridine- N -oxide Fe( iii ) intermediate has been detected as a potent oxidizing species for catalytic OAT reactions.
ISSN:1359-7345
1364-548X
DOI:10.1039/D1CC04521K