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Disproportionation of nitrogen induced by DC plasma-driven electrolysis in a nitrogen atmosphere
Nitrogen disproportionation i.e. its simultaneous conversion to compounds of higher (NO x ) and lower (NH 3 ) oxidation states in a N 2 DC plasma-driven electrolysis process with a plasma cathode is investigated. This type of plasma-liquid interaction exhibits a growing interest for many application...
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| Published in: | Green chemistry : an international journal and green chemistry resource : GC 2022-08, Vol.24 (18), p.71-7112 |
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| Main Authors: | , , , , , , , , , |
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| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c351t-d1d3c1afd4dffebf08e90a984679b4c29dcf17b8a71c6ce2025b19409e0161853 |
| container_end_page | 7112 |
| container_issue | 18 |
| container_start_page | 71 |
| container_title | Green chemistry : an international journal and green chemistry resource : GC |
| container_volume | 24 |
| creator | Pattyn, C Maira, N Buddhadasa, M Vervloessem, E Iseni, S Roy, N. C Remy, A Delplancke, M.-P De Geyter, N Reniers, F |
| description | Nitrogen disproportionation
i.e.
its simultaneous conversion to compounds of higher (NO
x
) and lower (NH
3
) oxidation states in a N
2
DC plasma-driven electrolysis process with a plasma cathode is investigated. This type of plasma-liquid interaction exhibits a growing interest for many applications, in particular nitrogen fixation where it represents a green alternative to the Haber-Bosch process. Optical emission spectroscopy, FTIR and electrochemical sensing systems are used to characterize the gas phase physico-chemistry while the liquid phase is analyzed
via
ionic chromatography and colorimetric assays. Experiments suggest that lowering the discharge current enhances nitrogen reduction and facilitates the transfer of nitrogen compounds to the liquid phase. Large amounts of water vapor appear to impact the gas discharge physico-chemistry and to favor the vibrational excitation of N
2
, a key parameter for an energy-efficient nitrogen fixation.
A simultaneous oxidation and reduction of nitrogen is performed for nitrogen fixation with a DC plasma-electrolysis operated in N
2
. |
| doi_str_mv | 10.1039/d2gc01013e |
| format | article |
| fullrecord | <record><control><sourceid>proquest_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_03766595v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2715888176</sourcerecordid><originalsourceid>FETCH-LOGICAL-c351t-d1d3c1afd4dffebf08e90a984679b4c29dcf17b8a71c6ce2025b19409e0161853</originalsourceid><addsrcrecordid>eNpF0c9LwzAUB_AiCs7pxbtQ8KRQzWvatDmObm7CwIueY5ofW0bX1KQb7L83s7JdkpB88nj5JoruAb0AwvRVpiuBAAFWF9EIMoITmhbo8rQm6XV04_0GIYCCZKPoe2p852xnXW9sy49DbHXcmt7ZlWpj08qdUDKuD_G0iruG-y1PpDP7cKYaJQJrDt74AGN-vsb7rfXdWjl1G11p3nh19z-Po6-32We1SJYf8_dqskwEzqFPJEgsgGuZSa1VrVGpKOK0zEhB60ykVAoNRV3yAgQRKkVpXgPNEFUICJQ5HkdPQ901b1jnzJa7A7PcsMVkyY57CBeE5DTfQ7CPgw0v_9kp37ON3bk2tMfSAvKyLEM4QT0PSjjrvVP6VBYQO6bNpum8-kt7FvDDgJ0XJ3f-DfwLHWB8SA</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2715888176</pqid></control><display><type>article</type><title>Disproportionation of nitrogen induced by DC plasma-driven electrolysis in a nitrogen atmosphere</title><source>Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list)</source><creator>Pattyn, C ; Maira, N ; Buddhadasa, M ; Vervloessem, E ; Iseni, S ; Roy, N. C ; Remy, A ; Delplancke, M.-P ; De Geyter, N ; Reniers, F</creator><creatorcontrib>Pattyn, C ; Maira, N ; Buddhadasa, M ; Vervloessem, E ; Iseni, S ; Roy, N. C ; Remy, A ; Delplancke, M.-P ; De Geyter, N ; Reniers, F</creatorcontrib><description>Nitrogen disproportionation
i.e.
its simultaneous conversion to compounds of higher (NO
x
) and lower (NH
3
) oxidation states in a N
2
DC plasma-driven electrolysis process with a plasma cathode is investigated. This type of plasma-liquid interaction exhibits a growing interest for many applications, in particular nitrogen fixation where it represents a green alternative to the Haber-Bosch process. Optical emission spectroscopy, FTIR and electrochemical sensing systems are used to characterize the gas phase physico-chemistry while the liquid phase is analyzed
via
ionic chromatography and colorimetric assays. Experiments suggest that lowering the discharge current enhances nitrogen reduction and facilitates the transfer of nitrogen compounds to the liquid phase. Large amounts of water vapor appear to impact the gas discharge physico-chemistry and to favor the vibrational excitation of N
2
, a key parameter for an energy-efficient nitrogen fixation.
A simultaneous oxidation and reduction of nitrogen is performed for nitrogen fixation with a DC plasma-electrolysis operated in N
2
.</description><identifier>ISSN: 1463-9262</identifier><identifier>EISSN: 1463-9270</identifier><identifier>DOI: 10.1039/d2gc01013e</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Ammonia ; Chemical Physics ; Colorimetry ; Disproportionation ; Electrochemistry ; Electrolysis ; Emission spectroscopy ; Energy efficiency ; Gas discharges ; Green chemistry ; Haber Bosch process ; Liquid phases ; Nitrogen compounds ; Nitrogen fixation ; Nitrogen plasma ; Nitrogenation ; Optical emission spectroscopy ; Oxidation ; Physics ; Plasma Physics ; Vapor phases ; Water vapor</subject><ispartof>Green chemistry : an international journal and green chemistry resource : GC, 2022-08, Vol.24 (18), p.71-7112</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><rights>Attribution - NonCommercial</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c351t-d1d3c1afd4dffebf08e90a984679b4c29dcf17b8a71c6ce2025b19409e0161853</citedby><cites>FETCH-LOGICAL-c351t-d1d3c1afd4dffebf08e90a984679b4c29dcf17b8a71c6ce2025b19409e0161853</cites><orcidid>0000-0003-0412-7597 ; 0000-0001-7883-5786 ; 0000-0002-4667-0662 ; 0000-0002-4923-1657</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://hal.science/hal-03766595$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Pattyn, C</creatorcontrib><creatorcontrib>Maira, N</creatorcontrib><creatorcontrib>Buddhadasa, M</creatorcontrib><creatorcontrib>Vervloessem, E</creatorcontrib><creatorcontrib>Iseni, S</creatorcontrib><creatorcontrib>Roy, N. C</creatorcontrib><creatorcontrib>Remy, A</creatorcontrib><creatorcontrib>Delplancke, M.-P</creatorcontrib><creatorcontrib>De Geyter, N</creatorcontrib><creatorcontrib>Reniers, F</creatorcontrib><title>Disproportionation of nitrogen induced by DC plasma-driven electrolysis in a nitrogen atmosphere</title><title>Green chemistry : an international journal and green chemistry resource : GC</title><description>Nitrogen disproportionation
i.e.
its simultaneous conversion to compounds of higher (NO
x
) and lower (NH
3
) oxidation states in a N
2
DC plasma-driven electrolysis process with a plasma cathode is investigated. This type of plasma-liquid interaction exhibits a growing interest for many applications, in particular nitrogen fixation where it represents a green alternative to the Haber-Bosch process. Optical emission spectroscopy, FTIR and electrochemical sensing systems are used to characterize the gas phase physico-chemistry while the liquid phase is analyzed
via
ionic chromatography and colorimetric assays. Experiments suggest that lowering the discharge current enhances nitrogen reduction and facilitates the transfer of nitrogen compounds to the liquid phase. Large amounts of water vapor appear to impact the gas discharge physico-chemistry and to favor the vibrational excitation of N
2
, a key parameter for an energy-efficient nitrogen fixation.
A simultaneous oxidation and reduction of nitrogen is performed for nitrogen fixation with a DC plasma-electrolysis operated in N
2
.</description><subject>Ammonia</subject><subject>Chemical Physics</subject><subject>Colorimetry</subject><subject>Disproportionation</subject><subject>Electrochemistry</subject><subject>Electrolysis</subject><subject>Emission spectroscopy</subject><subject>Energy efficiency</subject><subject>Gas discharges</subject><subject>Green chemistry</subject><subject>Haber Bosch process</subject><subject>Liquid phases</subject><subject>Nitrogen compounds</subject><subject>Nitrogen fixation</subject><subject>Nitrogen plasma</subject><subject>Nitrogenation</subject><subject>Optical emission spectroscopy</subject><subject>Oxidation</subject><subject>Physics</subject><subject>Plasma Physics</subject><subject>Vapor phases</subject><subject>Water vapor</subject><issn>1463-9262</issn><issn>1463-9270</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpF0c9LwzAUB_AiCs7pxbtQ8KRQzWvatDmObm7CwIueY5ofW0bX1KQb7L83s7JdkpB88nj5JoruAb0AwvRVpiuBAAFWF9EIMoITmhbo8rQm6XV04_0GIYCCZKPoe2p852xnXW9sy49DbHXcmt7ZlWpj08qdUDKuD_G0iruG-y1PpDP7cKYaJQJrDt74AGN-vsb7rfXdWjl1G11p3nh19z-Po6-32We1SJYf8_dqskwEzqFPJEgsgGuZSa1VrVGpKOK0zEhB60ykVAoNRV3yAgQRKkVpXgPNEFUICJQ5HkdPQ901b1jnzJa7A7PcsMVkyY57CBeE5DTfQ7CPgw0v_9kp37ON3bk2tMfSAvKyLEM4QT0PSjjrvVP6VBYQO6bNpum8-kt7FvDDgJ0XJ3f-DfwLHWB8SA</recordid><startdate>20220830</startdate><enddate>20220830</enddate><creator>Pattyn, C</creator><creator>Maira, N</creator><creator>Buddhadasa, M</creator><creator>Vervloessem, E</creator><creator>Iseni, S</creator><creator>Roy, N. C</creator><creator>Remy, A</creator><creator>Delplancke, M.-P</creator><creator>De Geyter, N</creator><creator>Reniers, F</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7ST</scope><scope>7U6</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>JG9</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0003-0412-7597</orcidid><orcidid>https://orcid.org/0000-0001-7883-5786</orcidid><orcidid>https://orcid.org/0000-0002-4667-0662</orcidid><orcidid>https://orcid.org/0000-0002-4923-1657</orcidid></search><sort><creationdate>20220830</creationdate><title>Disproportionation of nitrogen induced by DC plasma-driven electrolysis in a nitrogen atmosphere</title><author>Pattyn, C ; Maira, N ; Buddhadasa, M ; Vervloessem, E ; Iseni, S ; Roy, N. C ; Remy, A ; Delplancke, M.-P ; De Geyter, N ; Reniers, F</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c351t-d1d3c1afd4dffebf08e90a984679b4c29dcf17b8a71c6ce2025b19409e0161853</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Ammonia</topic><topic>Chemical Physics</topic><topic>Colorimetry</topic><topic>Disproportionation</topic><topic>Electrochemistry</topic><topic>Electrolysis</topic><topic>Emission spectroscopy</topic><topic>Energy efficiency</topic><topic>Gas discharges</topic><topic>Green chemistry</topic><topic>Haber Bosch process</topic><topic>Liquid phases</topic><topic>Nitrogen compounds</topic><topic>Nitrogen fixation</topic><topic>Nitrogen plasma</topic><topic>Nitrogenation</topic><topic>Optical emission spectroscopy</topic><topic>Oxidation</topic><topic>Physics</topic><topic>Plasma Physics</topic><topic>Vapor phases</topic><topic>Water vapor</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pattyn, C</creatorcontrib><creatorcontrib>Maira, N</creatorcontrib><creatorcontrib>Buddhadasa, M</creatorcontrib><creatorcontrib>Vervloessem, E</creatorcontrib><creatorcontrib>Iseni, S</creatorcontrib><creatorcontrib>Roy, N. C</creatorcontrib><creatorcontrib>Remy, A</creatorcontrib><creatorcontrib>Delplancke, M.-P</creatorcontrib><creatorcontrib>De Geyter, N</creatorcontrib><creatorcontrib>Reniers, F</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Materials Research Database</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pattyn, C</au><au>Maira, N</au><au>Buddhadasa, M</au><au>Vervloessem, E</au><au>Iseni, S</au><au>Roy, N. C</au><au>Remy, A</au><au>Delplancke, M.-P</au><au>De Geyter, N</au><au>Reniers, F</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Disproportionation of nitrogen induced by DC plasma-driven electrolysis in a nitrogen atmosphere</atitle><jtitle>Green chemistry : an international journal and green chemistry resource : GC</jtitle><date>2022-08-30</date><risdate>2022</risdate><volume>24</volume><issue>18</issue><spage>71</spage><epage>7112</epage><pages>71-7112</pages><issn>1463-9262</issn><eissn>1463-9270</eissn><abstract>Nitrogen disproportionation
i.e.
its simultaneous conversion to compounds of higher (NO
x
) and lower (NH
3
) oxidation states in a N
2
DC plasma-driven electrolysis process with a plasma cathode is investigated. This type of plasma-liquid interaction exhibits a growing interest for many applications, in particular nitrogen fixation where it represents a green alternative to the Haber-Bosch process. Optical emission spectroscopy, FTIR and electrochemical sensing systems are used to characterize the gas phase physico-chemistry while the liquid phase is analyzed
via
ionic chromatography and colorimetric assays. Experiments suggest that lowering the discharge current enhances nitrogen reduction and facilitates the transfer of nitrogen compounds to the liquid phase. Large amounts of water vapor appear to impact the gas discharge physico-chemistry and to favor the vibrational excitation of N
2
, a key parameter for an energy-efficient nitrogen fixation.
A simultaneous oxidation and reduction of nitrogen is performed for nitrogen fixation with a DC plasma-electrolysis operated in N
2
.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d2gc01013e</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0003-0412-7597</orcidid><orcidid>https://orcid.org/0000-0001-7883-5786</orcidid><orcidid>https://orcid.org/0000-0002-4667-0662</orcidid><orcidid>https://orcid.org/0000-0002-4923-1657</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1463-9262 |
| ispartof | Green chemistry : an international journal and green chemistry resource : GC, 2022-08, Vol.24 (18), p.71-7112 |
| issn | 1463-9262 1463-9270 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_03766595v1 |
| source | Royal Society of Chemistry:Jisc Collections:Royal Society of Chemistry Read and Publish 2022-2024 (reading list) |
| subjects | Ammonia Chemical Physics Colorimetry Disproportionation Electrochemistry Electrolysis Emission spectroscopy Energy efficiency Gas discharges Green chemistry Haber Bosch process Liquid phases Nitrogen compounds Nitrogen fixation Nitrogen plasma Nitrogenation Optical emission spectroscopy Oxidation Physics Plasma Physics Vapor phases Water vapor |
| title | Disproportionation of nitrogen induced by DC plasma-driven electrolysis in a nitrogen atmosphere |
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