A one-pot synthesis and X-Ray structural characterization of new highly substituted-allyl carbamates

•One-pot synthesis of new variously substituted allylic carbamates starting from β-chloro-α,β-unsaturated aldehydes in high yields.•Full characterization of the new compounds and the corresponding intermediates by NMR and IR spectroscopic techniques and HRMS.•X-ray crystallography structural determi...

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Bibliographic Details
Published in:Journal of molecular structure 2022-06, Vol.1258, p.132548, Article 132548
Main Authors: Ghrairi, Sondes, Retailleau, Pascal, Crousse, Benoit, Barhoumi Slimi, Thouraya
Format: Article
Language:English
Subjects:
Allylic carbamates
Chemical Sciences
One-pot synthesis
X-ray diffraction
β-chlorovinylaldehydes
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Summary:•One-pot synthesis of new variously substituted allylic carbamates starting from β-chloro-α,β-unsaturated aldehydes in high yields.•Full characterization of the new compounds and the corresponding intermediates by NMR and IR spectroscopic techniques and HRMS.•X-ray crystallography structural determination of two allyl carbamates. A one-pot synthesis of new variously substituted γ-chloro-γ, β-allylic carbamates have been carried out starting from β-chloro-α, β-unsaturated aldehydes. The new carbamates and the corresponding intermediates, the γ-chloro-γ, β-allylic alcohols, were fully characterized by (1H and 13C) NMR, IR and HRMS spectroscopic techniques. The crystal structures of two allylic carbamates, were established by single-crystal X-ray diffraction.
ISSN:0022-2860
1872-8014
0022-2860
DOI:10.1016/j.molstruc.2022.132548