Tailoring hydroxyapatite microspheres by spray-drying for powder bed fusion feedstock

• Published in: Powder technology 2022-01, Vol.398, p.117116, Article 117116
• Main Authors: Navarrete-Segado, P., Frances, C., Grossin, D., Tourbin, M.
• Format: Article
• Language: English
• Subjects: 3D printing; Air temperature; Chemical and Process Engineering; Chemical properties; Drying; Engineering Sciences; Feed rate; Flowability; Hydroxyapatite; Inlet temperature; Laser processing; Materials; Microspheres; Moisture effects; Parameters; Particle size; Particle size distribution; Physical characteristics; Physical properties; Physicochemical properties; Polyvinyl alcohol; Powder; Powder bed fusion; Powder beds; Rapid prototyping; Raw materials; Size distribution; Slurries; Spray-drying
• ISSN: 0032-5910; 1873-328X
• DOI: 10.1016/j.powtec.2022.117116

The present work deals with a study on the physical characteristics of stoichiometric hydroxyapatite microspheres produced by spray-drying process through different operating conditions. Obtained hydroxyapatite microspheres are intended to be used as powder feedstock in powder bed selective laser processing additive manufacturing technologies where the flowability and the particle size distribution of the powder feedstock are of special importance. The powders produced at different spray-drying operating parameters were evaluated by analysing the particle size, shape, moisture, and agglomerates strength. Spray air pressure (0.25–2 bars) and the solid content of the slurries (10–50% wt.) were the most influent parameters to control the final particle size distribution, whereas the higher process recovery rate (79%) was obtained at specific values of inlet temperature (250 °C), spray air pressure (2 bar), and feed rate (4.9 kg.h−1). A 5 wt% of polyvinyl alcohol as an organic binder to the ceramic part was found to increase the strength of the granules. The flowability of the produced hydroxyapatite microspheres (x50 = 64 μm; span = 1.77) was found to fulfil the defined feedstock requirements (e.g., Hausner ratio < 1.25), without alteration of the physico-chemical properties of the material. These promising results confirm the use of a spray dryer as an efficient method for the production of hydroxyapatite microspheres for powder bed selective laser processing. [Display omitted] •Powder bed fusion feedstock with improved flowability properties may be achieved by spray-drying process•Spray-drying process parameters can tune the hydroxyapatite microspheres particle size distribution•Polyvinyl alcohol as organic binder improves the granules breakage resistance•HA physico-chemical properties and crystallinity remain unaltered after the spray-drying process