Co-intercalation into graphite of lithium, potassium and barium using LiCl–KCl molten salt

The synthesis of a novel first stage GIC containing simultaneously lithium, potassium and barium through a solid–liquid reaction by molten salts method is described. Such a route has been largely developed in our laboratory for intercalation of metals into graphite. The interplanar distance of this...

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Published in:Carbon Letters 2023-08, Vol.33 (5), p.1303-1309
Main Authors: Hajj, Inass El, Speyer, Lucie, Cahen, Sébastien, Berger, Pascal, Medjahdi, Ghouti, Lagrange, Philippe, Claire Hérold
Format: Article
Language:English
Subjects:
Alloys
Analytical techniques
Barium
Carbon
Chemical Sciences
Graphene
Graphite
Heavy metals
Inorganic chemistry
Intercalation
Ion beams
Lithium
Lithium chloride
Metals
Molten salts
Nuclear reactors
Potassium
Potassium chloride
Scanning electron microscopy
Spectrum analysis
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cited_by cdi_FETCH-LOGICAL-c460t-3abe1383ee532eacfa4e219ff0f93dbeb6c109d33a9d98b0c8d9c2f904b389293
cites cdi_FETCH-LOGICAL-c460t-3abe1383ee532eacfa4e219ff0f93dbeb6c109d33a9d98b0c8d9c2f904b389293
container_end_page 1309
container_issue 5
container_start_page 1303
container_title Carbon Letters
container_volume 33
creator Hajj, Inass El
Speyer, Lucie
Cahen, Sébastien
Berger, Pascal
Medjahdi, Ghouti
Lagrange, Philippe
Claire Hérold
description The synthesis of a novel first stage GIC containing simultaneously lithium, potassium and barium through a solid–liquid reaction by molten salts method is described. Such a route has been largely developed in our laboratory for intercalation of metals into graphite. The interplanar distance of this quaternary compound reaches 950 pm and exhibits poly-layered intercalated sheets defined by X-ray measurements. The Li0.2K0.75Ba0.6C6 chemical formula of the compound is determined by ion beam analysis and this GIC is remarkably homogeneous. This GIC is the first poly-layered one containing barium.
doi_str_mv 10.1007/s42823-022-00352-8
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subjects Alloys
Analytical techniques
Barium
Carbon
Chemical Sciences
Graphene
Graphite
Heavy metals
Inorganic chemistry
Intercalation
Ion beams
Lithium
Lithium chloride
Metals
Molten salts
Nuclear reactors
Potassium
Potassium chloride
Scanning electron microscopy
Spectrum analysis
title Co-intercalation into graphite of lithium, potassium and barium using LiCl–KCl molten salt
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