Two Different Compounds in One Crystal: di-μ-chlorobis[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]diplatinum(II) and chloro(N,N-dimethylformamide-κO)[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]platinum(II)

The crystal structures of di-μ-chlorobis[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)] diplatinum(II) (1) and chloro(N,N-dimethylformamide-κO)[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]platinum(II) (2) have been determined by means of the X-ray diffraction. Both complexes cocrystallize in the monoclinic...

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Bibliographic Details
Published in:Journal of chemical crystallography 2023-06, Vol.53 (2), p.293-298
Main Authors: Sasaki, Isabelle, Mallet-Ladeira, Sonia
Format: Article
Language:English
Subjects:
Chemical Sciences
Chemistry
Chemistry and Materials Science
Coordination chemistry
Cristallography
Crystallization
Crystallography and Scattering Methods
Dimethylformamide
Inorganic Chemistry
Organometallic Chemistry
Original Paper
Physical Chemistry
Platinum
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Summary:The crystal structures of di-μ-chlorobis[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)] diplatinum(II) (1) and chloro(N,N-dimethylformamide-κO)[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]platinum(II) (2) have been determined by means of the X-ray diffraction. Both complexes cocrystallize in the monoclinic space group C2/c with a  = 39.5457(18) Å, b  = 7.2482(4) Å, c  = 21.2269(10) Å and β = 121.460(2)°. The asymmetric unit consists of half a centrosymmetric compound (complex 1 ) and one full independent compound (complex 2 ). Graphical Abstract The X-ray structures of co-crystallized di-μ-chlorobis[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]diplatinum(II) (1) as starting material and of the derivative chloro(N,N-dimethylformamide-κO)[2-(5-methyl-pyridin-2-yl-κN)phenyl-κC(1)]platinum(II) (2) are reported.
ISSN:1074-1542
1572-8854
DOI:10.1007/s10870-022-00970-0