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Voltammetric study of the affinity of divalent heavy metals for guanine-functionalized iron oxide nanoparticles
In this study, a novel nanobiomaterial based on (3-aminopropyl)triethoxysilane (APTES)-coated iron oxide (Fe 3 O 4 ) nanoparticles functionalized with newly synthesized guanine hydrazide (GH) was elaborated. A boron-doped diamond electrode coated with GH-APTES–Fe 3 O 4 nanoparticles was used to asse...
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Published in: | Monatshefte für Chemie 2021-02, Vol.152 (2), p.229-240 |
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container_title | Monatshefte für Chemie |
container_volume | 152 |
creator | Sawan, Simona Hamze, Khalil Youssef, Ali Boukarroum, Rayyan Bouhadir, Kamal Errachid, Abdelhamid Maalouf, Rita Jaffrezic-Renault, Nicole |
description | In this study, a novel nanobiomaterial based on (3-aminopropyl)triethoxysilane (APTES)-coated iron oxide (Fe
3
O
4
) nanoparticles functionalized with newly synthesized guanine hydrazide (GH) was elaborated. A boron-doped diamond electrode coated with GH-APTES–Fe
3
O
4
nanoparticles was used to assess the interaction of heavy metal ions with guanine hydrazide. The adsorption isotherms were electrochemically investigated and it was shown that the adsorption capacity of the nanoparticles towards heavy metals decreased in the following order: Cu
2+
> Pb
2+
> Cd
2+
. From the calibration curves, the sensitivities of detection were as follows: 171.6 µA/µM for Cu(II), 156 µA/µM for Pb(II), and 101.4 µA/µM for Cd(II).
Graphic abstract |
doi_str_mv | 10.1007/s00706-021-02738-2 |
format | article |
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3
O
4
) nanoparticles functionalized with newly synthesized guanine hydrazide (GH) was elaborated. A boron-doped diamond electrode coated with GH-APTES–Fe
3
O
4
nanoparticles was used to assess the interaction of heavy metal ions with guanine hydrazide. The adsorption isotherms were electrochemically investigated and it was shown that the adsorption capacity of the nanoparticles towards heavy metals decreased in the following order: Cu
2+
> Pb
2+
> Cd
2+
. From the calibration curves, the sensitivities of detection were as follows: 171.6 µA/µM for Cu(II), 156 µA/µM for Pb(II), and 101.4 µA/µM for Cd(II).
Graphic abstract</description><identifier>ISSN: 0026-9247</identifier><identifier>EISSN: 1434-4475</identifier><identifier>DOI: 10.1007/s00706-021-02738-2</identifier><language>eng</language><publisher>Vienna: Springer Vienna</publisher><subject>Adsorption ; Aminopropyltriethoxysilane ; Analytical Chemistry ; Biomedical materials ; Boron ; Chemical Sciences ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Coated electrodes ; Coordination chemistry ; Copper ; Diamond films ; Diamonds ; Heavy metals ; Inorganic Chemistry ; Iron oxides ; Material chemistry ; Nanomaterials ; Nanoparticles ; Organic Chemistry ; Original Paper ; Physical Chemistry ; Theoretical and Computational Chemistry</subject><ispartof>Monatshefte für Chemie, 2021-02, Vol.152 (2), p.229-240</ispartof><rights>Springer-Verlag GmbH Austria, part of Springer Nature 2021</rights><rights>Springer-Verlag GmbH Austria, part of Springer Nature 2021.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c390t-b7de474313698bb3b16a7dafaabd8147b374e3991aba432589b31d787ca575d03</citedby><cites>FETCH-LOGICAL-c390t-b7de474313698bb3b16a7dafaabd8147b374e3991aba432589b31d787ca575d03</cites><orcidid>0000-0003-1354-9273</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://hal.science/hal-03997025$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Sawan, Simona</creatorcontrib><creatorcontrib>Hamze, Khalil</creatorcontrib><creatorcontrib>Youssef, Ali</creatorcontrib><creatorcontrib>Boukarroum, Rayyan</creatorcontrib><creatorcontrib>Bouhadir, Kamal</creatorcontrib><creatorcontrib>Errachid, Abdelhamid</creatorcontrib><creatorcontrib>Maalouf, Rita</creatorcontrib><creatorcontrib>Jaffrezic-Renault, Nicole</creatorcontrib><title>Voltammetric study of the affinity of divalent heavy metals for guanine-functionalized iron oxide nanoparticles</title><title>Monatshefte für Chemie</title><addtitle>Monatsh Chem</addtitle><description>In this study, a novel nanobiomaterial based on (3-aminopropyl)triethoxysilane (APTES)-coated iron oxide (Fe
3
O
4
) nanoparticles functionalized with newly synthesized guanine hydrazide (GH) was elaborated. A boron-doped diamond electrode coated with GH-APTES–Fe
3
O
4
nanoparticles was used to assess the interaction of heavy metal ions with guanine hydrazide. The adsorption isotherms were electrochemically investigated and it was shown that the adsorption capacity of the nanoparticles towards heavy metals decreased in the following order: Cu
2+
> Pb
2+
> Cd
2+
. From the calibration curves, the sensitivities of detection were as follows: 171.6 µA/µM for Cu(II), 156 µA/µM for Pb(II), and 101.4 µA/µM for Cd(II).
Graphic abstract</description><subject>Adsorption</subject><subject>Aminopropyltriethoxysilane</subject><subject>Analytical Chemistry</subject><subject>Biomedical materials</subject><subject>Boron</subject><subject>Chemical Sciences</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Coated electrodes</subject><subject>Coordination chemistry</subject><subject>Copper</subject><subject>Diamond films</subject><subject>Diamonds</subject><subject>Heavy metals</subject><subject>Inorganic Chemistry</subject><subject>Iron oxides</subject><subject>Material chemistry</subject><subject>Nanomaterials</subject><subject>Nanoparticles</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Theoretical and Computational Chemistry</subject><issn>0026-9247</issn><issn>1434-4475</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp9kctKxDAUhoMoOF5ewFXAlYtqbp00SxFvMOBG3YbTJnUinWRM0sHx6Y1WdOciCSd83w-HH6ETSs4pIfIilYvMK8JoOZI3FdtBMyq4qISQ9S6aEcLmlWJC7qODlF5JmQXhMxSew5BhtbI5ug6nPJotDj3OS4uh7513-Xs2bgOD9RkvLWy2uOAwJNyHiF9G8M7bqh99l13wMLgPa7CLwePw7ozFHnxYQ8yuG2w6Qnt9Ue3xz3uInm6uH6_uqsXD7f3V5aLquCK5aqWxQgpO-Vw1bctbOgdpoAdoTUOFbLkUlitFoQXBWd2ollMjG9lBLWtD-CE6m3KXMOh1dCuIWx3A6bvLhf76I8WWhNUbWtjTiV3H8DbalPVrGGPZJGkmFFeyJkoWik1UF0NK0fa_sZTorxL0VIIuJejvEjQrEp-kVGD_YuNf9D_WJ3i1iyY</recordid><startdate>20210201</startdate><enddate>20210201</enddate><creator>Sawan, Simona</creator><creator>Hamze, Khalil</creator><creator>Youssef, Ali</creator><creator>Boukarroum, Rayyan</creator><creator>Bouhadir, Kamal</creator><creator>Errachid, Abdelhamid</creator><creator>Maalouf, Rita</creator><creator>Jaffrezic-Renault, Nicole</creator><general>Springer Vienna</general><general>Springer Nature B.V</general><general>Springer Verlag</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0003-1354-9273</orcidid></search><sort><creationdate>20210201</creationdate><title>Voltammetric study of the affinity of divalent heavy metals for guanine-functionalized iron oxide nanoparticles</title><author>Sawan, Simona ; Hamze, Khalil ; Youssef, Ali ; Boukarroum, Rayyan ; Bouhadir, Kamal ; Errachid, Abdelhamid ; Maalouf, Rita ; Jaffrezic-Renault, Nicole</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c390t-b7de474313698bb3b16a7dafaabd8147b374e3991aba432589b31d787ca575d03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Adsorption</topic><topic>Aminopropyltriethoxysilane</topic><topic>Analytical Chemistry</topic><topic>Biomedical materials</topic><topic>Boron</topic><topic>Chemical Sciences</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Coated electrodes</topic><topic>Coordination chemistry</topic><topic>Copper</topic><topic>Diamond films</topic><topic>Diamonds</topic><topic>Heavy metals</topic><topic>Inorganic Chemistry</topic><topic>Iron oxides</topic><topic>Material chemistry</topic><topic>Nanomaterials</topic><topic>Nanoparticles</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Theoretical and Computational Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sawan, Simona</creatorcontrib><creatorcontrib>Hamze, Khalil</creatorcontrib><creatorcontrib>Youssef, Ali</creatorcontrib><creatorcontrib>Boukarroum, Rayyan</creatorcontrib><creatorcontrib>Bouhadir, Kamal</creatorcontrib><creatorcontrib>Errachid, Abdelhamid</creatorcontrib><creatorcontrib>Maalouf, Rita</creatorcontrib><creatorcontrib>Jaffrezic-Renault, Nicole</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Monatshefte für Chemie</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sawan, Simona</au><au>Hamze, Khalil</au><au>Youssef, Ali</au><au>Boukarroum, Rayyan</au><au>Bouhadir, Kamal</au><au>Errachid, Abdelhamid</au><au>Maalouf, Rita</au><au>Jaffrezic-Renault, Nicole</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Voltammetric study of the affinity of divalent heavy metals for guanine-functionalized iron oxide nanoparticles</atitle><jtitle>Monatshefte für Chemie</jtitle><stitle>Monatsh Chem</stitle><date>2021-02-01</date><risdate>2021</risdate><volume>152</volume><issue>2</issue><spage>229</spage><epage>240</epage><pages>229-240</pages><issn>0026-9247</issn><eissn>1434-4475</eissn><abstract>In this study, a novel nanobiomaterial based on (3-aminopropyl)triethoxysilane (APTES)-coated iron oxide (Fe
3
O
4
) nanoparticles functionalized with newly synthesized guanine hydrazide (GH) was elaborated. A boron-doped diamond electrode coated with GH-APTES–Fe
3
O
4
nanoparticles was used to assess the interaction of heavy metal ions with guanine hydrazide. The adsorption isotherms were electrochemically investigated and it was shown that the adsorption capacity of the nanoparticles towards heavy metals decreased in the following order: Cu
2+
> Pb
2+
> Cd
2+
. From the calibration curves, the sensitivities of detection were as follows: 171.6 µA/µM for Cu(II), 156 µA/µM for Pb(II), and 101.4 µA/µM for Cd(II).
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language | eng |
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subjects | Adsorption Aminopropyltriethoxysilane Analytical Chemistry Biomedical materials Boron Chemical Sciences Chemistry Chemistry and Materials Science Chemistry/Food Science Coated electrodes Coordination chemistry Copper Diamond films Diamonds Heavy metals Inorganic Chemistry Iron oxides Material chemistry Nanomaterials Nanoparticles Organic Chemistry Original Paper Physical Chemistry Theoretical and Computational Chemistry |
title | Voltammetric study of the affinity of divalent heavy metals for guanine-functionalized iron oxide nanoparticles |
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