Photocatalytic degradation of paracetamol mediating luminous textile: Intensification of the chemical oxidation

• Published in: Journal of water process engineering 2023-07, Vol.53, p.103648, Article 103648
• Main Authors: Dhibi, Houda, Guiza, Monia, Bouzaza, Abdelkrim, Ouederni, Abdelmottaleb, Lamaa, Lina, Péruchon, Laure, Brochier, Cédric, Amrane, Abdeltif, Loganathan, Sivachandiran, Rtimi, Sami, Assadi, Aymen Amin
• Format: Article
• Language: English
• Subjects: Cellulosic paper; Chemical Sciences; Luminous textile; Paracetamol degradation; Photocatalysis; Water pollution
• ISSN: 2214-7144; 2214-7144
• DOI: 10.1016/j.jwpe.2023.103648

An innovative photoreactor was applied as an emerging advanced oxidation process (AOP) to investigate Paracetamol (PL) degradation under different operating conditions. The system consisted of a textile woven from optical fiber and textile yarn. The luminous fiber textile was coupled to UVA LED, and the photocatalytic textile fibers is impregnated with TiO2. The effectiveness of configuration I, based on a luminous textile with UV LED, was compared with that based of TiO2 immobilized on cellulosic paper (CP) with external UV irradiation (configuration 2). The specific degradation rate obtained with configuration 1 was 40 times higher than that with configuration II. Configuration I also showed efficient performance in mineralization per Watt consumed, with values reaching 81 times higher than those obtained with configuration II. Also, to achieve high removal efficiency of the pollutant with the new technology of luminous textiles, the effect of operating parameters, namely pollutant concentration, UV intensity, flow rate and TiO2 mass deposited were discussed. It is worth noting that the optimal conditions for a 95.7 % degradation rate of 1 mg/L of Paracetamol were obtained with 26 g/m2 mass catalyst, 5 W/m2 UV intensity and 52.2 L/h flow rate after 340 min. In addition, upon associating two luminous textiles, the degradation efficiency reached 98.76 % after only 140 min. Besides, by adding hydrogen peroxide (H2O2) in the optimal conditions with 10 mg/L of Paracetamol concentration, the degradation efficiency reached 98.81 % after 240 min. The excellent performances in terms of degradation rate, mineralization per Watt consumed, and energy consumption make luminous textiles an attractive alternative to conventional photocatalytic reactors designed for the removal of Paracetamol in water and wastewater. [Display omitted] •TiO2 supported Luminous textiles exhibited an excellent degradation rate.•TiO2 loading and uniform dispersion increased the paracetamol removal.•Addition of oxidant H2O2 improved the paracetamol removal and mineralization.•Paracetamol degradation is well fitted with Langmuir-Hinshelwood model