Canted ferrimagnetism in the distorted double perovskite La3Mn2NbO9

• Published in: Journal of alloys and compounds 2021-02, Vol.854, p.157018, Article 157018
• Main Authors: Arciniegas Jaimes, Diana M., Fuertes, Valeria C., Blanco, M. Cecilia, Tirao, Germán, Limandri, Silvina, Nassif, Vivian M., Cuello, Gabriel J., Rodríguez, Alejandro, Reguera, Edilso, Carbonio, Raúl E.
• Format: Article
• Language: English
• Subjects: Antiferromagnetism; Canted ferrimagnetism; Cations; Crystal structure; Crystals; Double perovskite; Ferrimagnetism; Ferromagnetism; Filing; Magnetic measurements; Magnetic moments; Magnetic properties; Neutron diffraction; Neutrons; Perovskites; Photoelectrons; Physics; Room temperature; Spectrum analysis; Spin structure; Structural analysis; Unit cell; X ray photoelectron spectroscopy; X-ray emission spectroscopy
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2020.157018

The synthesis, structural characterization, and magnetic properties of La3Mn2NbO9 double perovskite are reported. The crystal structure has been refined by X-ray and neutron powder diffraction data in the monoclinic space group P21/n. The Mn2+, Mn3+ and Nb5+ cations are distributed at the 2d and 2c Wyckoff sites, with a high cation order degree in the latter, mainly occupied by Mn2+/Mn3+. The Mn3+ presence was established from X-ray Emission Spectroscopy and X-ray Photoelectron Spectroscopy. Rietveld refinements of powder neutron diffraction data show that at room temperature the cell parameters are a= 5.6063(3) Å, b= 5.8155(3) Å, c= 7.9877(2) Å y β= 89.89(1)°. Magnetization measurements indicate the presence of ferromagnetic and antiferromagnetic interactions with TC ∼19 K and TN ∼11 K, respectively, with a magnetic cell of symmetry Γ1(Ag). The analysis of the neutron data suggests a canted ferrimagnetic spin structure where an antiferromagnetic unit-cell in a and c axis, and ferromagnetic in b axis with a propagation vector k= (0 ½ 0) was used. The effective magnetic moment obtained experimentally is μeff= 5.50 μB/mol Mn2+/3+, slightly lower than the theoretical one for spin only (5.83 μB). •Synthesis of new double perovskite La3Mn2NbO9.•Canted ferrimagnetism due to the high degree of structural distortion.•Effective existence of Mn2+/Mn3+ mixture.•Multiple possible magnetic interactions and huge distortion of the octahedral network allow AFM and FM couplings.