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Herbs carbonization and activation for fast sorption of nitrate ions: a new challenge for a full treatment of groundwater pollution
The evolution of low-cost ecotechnologies in water treatment and purification is highly increased. Face to the growing global demand for eco-friendly water treatment materials, the non-valorized herb-based biomass covering a large area could be a promising alternative. Herbs (HB) are currently one o...
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Published in: | Environmental science and pollution research international 2023-07, Vol.30 (34), p.82637-82646 |
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container_issue | 34 |
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container_title | Environmental science and pollution research international |
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creator | Vieillard, Julien Bouazizi, Nabil Fotsing, Patrick Nkuigue Samir, Brahim Raguillet, Kevin Cosme, Julie Serhal, Cynthia Abou Mignot, Melanie Bette, Marie Sophie Auger, Patrick Dotto, Guilherme Luiz Le Derf, Franck |
description | The evolution of low-cost ecotechnologies in water treatment and purification is highly increased. Face to the growing global demand for eco-friendly water treatment materials, the non-valorized herb-based biomass covering a large area could be a promising alternative. Herbs (HB) are currently one of the cheapest biomasses. Therefore, the utilization of HB for environmental applications is relevant. HB was treated and activated in this work to produce an eco-friendly adsorbent for nitrate removal from groundwater. HB was treated with modified carbonization at 220 °C to produce highly reactive biochar (BCH). Ammonium groups (AM) are immobilized covalently over the BCH surface, and then, the resulting materials BCH-AM are fully characterized. Results showed that ammonium is successfully grafted at the BCH surface, producing a highly stable material. Measurements on nitrate ion adsorption revealed that BCH-AM are of great interest as 80% of nitrate ions (NO
3
−
) were removed. Importantly, the eco-friendly BCH-AM demonstrated the ability to easily desorb the nitrate ions using Na
2
CO
3
as a green eluent. Parametric studies confirmed the effectiveness of the prepared adsorbent and approved that the adsorption occurred by electrostatic interactions. To demonstrate the performance of the adsorbent, BCH-AM was evaluated to remove NO
3
−
from groundwater upstream in a water treatment plant. This work opens an immense perspective for herb biomass to be the actual challenge to resolve environmental problems. |
doi_str_mv | 10.1007/s11356-023-28282-6 |
format | article |
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3
−
) were removed. Importantly, the eco-friendly BCH-AM demonstrated the ability to easily desorb the nitrate ions using Na
2
CO
3
as a green eluent. Parametric studies confirmed the effectiveness of the prepared adsorbent and approved that the adsorption occurred by electrostatic interactions. To demonstrate the performance of the adsorbent, BCH-AM was evaluated to remove NO
3
−
from groundwater upstream in a water treatment plant. This work opens an immense perspective for herb biomass to be the actual challenge to resolve environmental problems.</description><identifier>ISSN: 1614-7499</identifier><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-023-28282-6</identifier><identifier>PMID: 37328728</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Adsorbents ; Adsorption ; Ammonium ; Ammonium Compounds ; Aquatic Pollution ; Atmospheric Protection/Air Quality Control/Air Pollution ; Biomass ; Carbonization ; Charcoal ; Chemical Sciences ; Earth and Environmental Science ; Ecotoxicology ; Electrostatic properties ; Environment ; Environmental Chemistry ; Environmental Health ; Environmental impact ; Environmental Pollution ; Environmental science ; Groundwater ; Groundwater pollution ; Groundwater treatment ; Herbs ; Ion adsorption ; Ions ; Kinetics ; Nitrate removal ; Nitrates ; Nutrient removal ; Research Article ; Sodium carbonate ; Surface chemistry ; Waste Water Technology ; Water Management ; Water Pollutants, Chemical ; Water Pollution Control ; Water pollution treatment ; Water purification ; Water treatment ; Water treatment plants</subject><ispartof>Environmental science and pollution research international, 2023-07, Vol.30 (34), p.82637-82646</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c409t-83865c6e5a8bc5cd22fad1d292daa2c8ef026776845e310903d696522b3e402a3</citedby><cites>FETCH-LOGICAL-c409t-83865c6e5a8bc5cd22fad1d292daa2c8ef026776845e310903d696522b3e402a3</cites><orcidid>0000-0002-4413-8138 ; 0000-0003-3781-2830</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2837644794/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2837644794?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>230,314,780,784,885,11687,27923,27924,36059,36060,44362,74666</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/37328728$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-04429889$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Vieillard, Julien</creatorcontrib><creatorcontrib>Bouazizi, Nabil</creatorcontrib><creatorcontrib>Fotsing, Patrick Nkuigue</creatorcontrib><creatorcontrib>Samir, Brahim</creatorcontrib><creatorcontrib>Raguillet, Kevin</creatorcontrib><creatorcontrib>Cosme, Julie</creatorcontrib><creatorcontrib>Serhal, Cynthia Abou</creatorcontrib><creatorcontrib>Mignot, Melanie</creatorcontrib><creatorcontrib>Bette, Marie Sophie</creatorcontrib><creatorcontrib>Auger, Patrick</creatorcontrib><creatorcontrib>Dotto, Guilherme Luiz</creatorcontrib><creatorcontrib>Le Derf, Franck</creatorcontrib><title>Herbs carbonization and activation for fast sorption of nitrate ions: a new challenge for a full treatment of groundwater pollution</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><addtitle>Environ Sci Pollut Res Int</addtitle><description>The evolution of low-cost ecotechnologies in water treatment and purification is highly increased. Face to the growing global demand for eco-friendly water treatment materials, the non-valorized herb-based biomass covering a large area could be a promising alternative. Herbs (HB) are currently one of the cheapest biomasses. Therefore, the utilization of HB for environmental applications is relevant. HB was treated and activated in this work to produce an eco-friendly adsorbent for nitrate removal from groundwater. HB was treated with modified carbonization at 220 °C to produce highly reactive biochar (BCH). Ammonium groups (AM) are immobilized covalently over the BCH surface, and then, the resulting materials BCH-AM are fully characterized. Results showed that ammonium is successfully grafted at the BCH surface, producing a highly stable material. Measurements on nitrate ion adsorption revealed that BCH-AM are of great interest as 80% of nitrate ions (NO
3
−
) were removed. Importantly, the eco-friendly BCH-AM demonstrated the ability to easily desorb the nitrate ions using Na
2
CO
3
as a green eluent. Parametric studies confirmed the effectiveness of the prepared adsorbent and approved that the adsorption occurred by electrostatic interactions. To demonstrate the performance of the adsorbent, BCH-AM was evaluated to remove NO
3
−
from groundwater upstream in a water treatment plant. This work opens an immense perspective for herb biomass to be the actual challenge to resolve environmental problems.</description><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Ammonium</subject><subject>Ammonium Compounds</subject><subject>Aquatic Pollution</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Biomass</subject><subject>Carbonization</subject><subject>Charcoal</subject><subject>Chemical Sciences</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Electrostatic properties</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Environmental impact</subject><subject>Environmental Pollution</subject><subject>Environmental science</subject><subject>Groundwater</subject><subject>Groundwater pollution</subject><subject>Groundwater treatment</subject><subject>Herbs</subject><subject>Ion adsorption</subject><subject>Ions</subject><subject>Kinetics</subject><subject>Nitrate removal</subject><subject>Nitrates</subject><subject>Nutrient removal</subject><subject>Research Article</subject><subject>Sodium carbonate</subject><subject>Surface chemistry</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollutants, Chemical</subject><subject>Water Pollution Control</subject><subject>Water pollution treatment</subject><subject>Water purification</subject><subject>Water treatment</subject><subject>Water treatment 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carbonization and activation for fast sorption of nitrate ions: a new challenge for a full treatment of groundwater pollution</title><author>Vieillard, Julien ; Bouazizi, Nabil ; Fotsing, Patrick Nkuigue ; Samir, Brahim ; Raguillet, Kevin ; Cosme, Julie ; Serhal, Cynthia Abou ; Mignot, Melanie ; Bette, Marie Sophie ; Auger, Patrick ; Dotto, Guilherme Luiz ; Le Derf, Franck</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c409t-83865c6e5a8bc5cd22fad1d292daa2c8ef026776845e310903d696522b3e402a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Ammonium</topic><topic>Ammonium Compounds</topic><topic>Aquatic Pollution</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Biomass</topic><topic>Carbonization</topic><topic>Charcoal</topic><topic>Chemical Sciences</topic><topic>Earth and Environmental 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pollution</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><addtitle>Environ Sci Pollut Res Int</addtitle><date>2023-07-01</date><risdate>2023</risdate><volume>30</volume><issue>34</issue><spage>82637</spage><epage>82646</epage><pages>82637-82646</pages><issn>1614-7499</issn><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>The evolution of low-cost ecotechnologies in water treatment and purification is highly increased. Face to the growing global demand for eco-friendly water treatment materials, the non-valorized herb-based biomass covering a large area could be a promising alternative. Herbs (HB) are currently one of the cheapest biomasses. Therefore, the utilization of HB for environmental applications is relevant. HB was treated and activated in this work to produce an eco-friendly adsorbent for nitrate removal from groundwater. HB was treated with modified carbonization at 220 °C to produce highly reactive biochar (BCH). Ammonium groups (AM) are immobilized covalently over the BCH surface, and then, the resulting materials BCH-AM are fully characterized. Results showed that ammonium is successfully grafted at the BCH surface, producing a highly stable material. Measurements on nitrate ion adsorption revealed that BCH-AM are of great interest as 80% of nitrate ions (NO
3
−
) were removed. Importantly, the eco-friendly BCH-AM demonstrated the ability to easily desorb the nitrate ions using Na
2
CO
3
as a green eluent. Parametric studies confirmed the effectiveness of the prepared adsorbent and approved that the adsorption occurred by electrostatic interactions. To demonstrate the performance of the adsorbent, BCH-AM was evaluated to remove NO
3
−
from groundwater upstream in a water treatment plant. This work opens an immense perspective for herb biomass to be the actual challenge to resolve environmental problems.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>37328728</pmid><doi>10.1007/s11356-023-28282-6</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-4413-8138</orcidid><orcidid>https://orcid.org/0000-0003-3781-2830</orcidid></addata></record> |
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identifier | ISSN: 1614-7499 |
ispartof | Environmental science and pollution research international, 2023-07, Vol.30 (34), p.82637-82646 |
issn | 1614-7499 0944-1344 1614-7499 |
language | eng |
recordid | cdi_hal_primary_oai_HAL_hal_04429889v1 |
source | ABI/INFORM Collection; Springer Nature |
subjects | Adsorbents Adsorption Ammonium Ammonium Compounds Aquatic Pollution Atmospheric Protection/Air Quality Control/Air Pollution Biomass Carbonization Charcoal Chemical Sciences Earth and Environmental Science Ecotoxicology Electrostatic properties Environment Environmental Chemistry Environmental Health Environmental impact Environmental Pollution Environmental science Groundwater Groundwater pollution Groundwater treatment Herbs Ion adsorption Ions Kinetics Nitrate removal Nitrates Nutrient removal Research Article Sodium carbonate Surface chemistry Waste Water Technology Water Management Water Pollutants, Chemical Water Pollution Control Water pollution treatment Water purification Water treatment Water treatment plants |
title | Herbs carbonization and activation for fast sorption of nitrate ions: a new challenge for a full treatment of groundwater pollution |
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