Synthesis and characterization of analogues of glycine-betaine ionic liquids with the 4-chlorosalicylate anion and their use in the extraction of copper() ions

A series of 5 analogues of glycine-betaine based ionic liquids (AGB-ILs) viz. [tri( n -butyl)(2-alkoxy-2-oxoethyl)]ammonium (alkoxy = n -butoxy, n -pentoxy, n -hexoxy, n -heptoxy and n -octoxy) associated with the 4-chlorosalicylate anion have been synthesized and fully characterized by spectroscopi...

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Bibliographic Details
Published in:New journal of chemistry 2019, Vol.43 (37), p.14818-14828
Main Authors: Diabate, Pape Diaba, Boudesocque, Stéphanie, Kowandy, Christelle, Dupont, Laurent, Mohamadou, Aminou
Format: Article
Language:English
Subjects:
Anions
Cations
Chains
Chemical analysis
Chemical Sciences
Copper
Copper compounds
Fluorescence
Glycine
Ionic liquids
Ions
NMR
Nuclear magnetic resonance
Photoluminescence
Solvents
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Summary:A series of 5 analogues of glycine-betaine based ionic liquids (AGB-ILs) viz. [tri( n -butyl)(2-alkoxy-2-oxoethyl)]ammonium (alkoxy = n -butoxy, n -pentoxy, n -hexoxy, n -heptoxy and n -octoxy) associated with the 4-chlorosalicylate anion have been synthesized and fully characterized by spectroscopic methods (IR, 1 H and 13 C NMR) and elemental analysis. The effect of the alkyl chain length of the cation core on the physicochemical properties of these ionic liquids has been investigated. The photoluminescence study of these AGB-ILs shows that the nature of the organic cation does not have a great influence on their fluorescence induced by the 4-chlorosalicylate anion. The extraction ability of these ionic solvents towards different aqueous copper( ii ) salts was investigated. It was found that the copper extraction yield with these AGB-ILs depends not only on the length of the alkyl chain (the shorter the alkyl chain, the higher the extraction yield) but mostly on the nature of the counter-anion of the copper( ii ) salt; this extraction yield decreases in the order ClO 4 − > NO 3 − > Cl − > SO 4 2− . The mechanism studied shows that ion pairing extraction is especially favoured by AGB-ILs possessing long alkyl chains. 5 analogues of glycine-betainium associated with the 4-chlorosalicylate anion have been synthesized and their used in the extraction of aqueous Cu 2+ ions show that the extraction efficiency depends much more on the nature of the metal counter ion.
ISSN:1144-0546
1369-9261
DOI:10.1039/c9nj01847f