1- and 2-D Coordination Networks Based on Porphyrin and Copper: an Example of Supramolecular Isomerism

A high‐yield synthesis of atropoisomers of the meso‐tetrakis(o‐isonicotinoylamidophenyl)porphyrin was achieved. Depending on the crystallising solvent system, the α2β2 atropoisomer leads to the formation of either 1‐D or 2‐D coordination networks in the presence of Cu(OAc)2.

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Bibliographic Details
Published in:European journal of inorganic chemistry 2002-12, Vol.2002 (12), p.3079-3082
Main Authors: Zimmer, Bertrand, Bulach, Véronique, Hosseini, Mir Wais, De Cian, André, Kyritsakas, Nathalie
Format: Article
Language:English
Subjects:
Atropoisomerism
Chemical Sciences
Coordination chemistry
Coordination network
Copper
Isonicotinoyl
Porphyrin
Pyridine
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Description
Summary:A high‐yield synthesis of atropoisomers of the meso‐tetrakis(o‐isonicotinoylamidophenyl)porphyrin was achieved. Depending on the crystallising solvent system, the α2β2 atropoisomer leads to the formation of either 1‐D or 2‐D coordination networks in the presence of Cu(OAc)2.
ISSN:1434-1948
1099-0682
DOI:10.1002/1099-0682(200212)2002:12<3079::AID-EJIC3079>3.0.CO;2-R