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From normal ferroelectric transition to relaxor behavior in Aurivillius ferroelectric ceramics
The influence of the barium concentration on the dielectric response of Sr 1− x Ba x Bi 2 Nb 2 O 9 system, with x = 0, 15, 30, 50, 70, 85, 100 at.%, has been studied. The barium concentration dependence of T m , as well as the temperature of the corresponding maximum for the real part of the dielec...
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Published in: | Journal of materials science 2014-11, Vol.49 (21), p.7437-7444 |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | The influence of the barium concentration on the dielectric response of Sr
1−
x
Ba
x
Bi
2
Nb
2
O
9
system, with
x
= 0, 15, 30, 50, 70, 85, 100 at.%, has been studied. The barium concentration dependence of
T
m
, as well as the temperature of the corresponding maximum for the real part of the dielectric permittivity, has suggested a cation site mixing among atomic positions, which has been supported by the structural analysis. A transition from normal ferroelectric–paraelectric phase transition to a relaxor behavior has been observed in the studied samples, when the barium concentration has increased. The relaxor behavior has been discussed. |
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ISSN: | 0022-2461 1573-4803 |
DOI: | 10.1007/s10853-014-8448-0 |