Review on analytical methods and occurrence of organic contaminants in continental water sediments

• Published in: Chemosphere (Oxford) 2024-10, Vol.365, p.143275, Article 143275
• Main Authors: Ducrocq, Tom, Merel, Sylvain, Miège, Cécile
• Format: Article
• Language: English
• Subjects: Aquatic environment; Chemical Sciences; Emerging contaminants; Environmental Sciences; Mass spectrometry; Non-target analysis; Sediment contaminants database; Suspended particulate matter
• ISSN: 0045-6535; 1879-1298; 1879-1298
• DOI: 10.1016/j.chemosphere.2024.143275

Various industries produce a myriad of synthetic molecules used to satisfy our needs, but all these molecules are likely to reach aquatic environments. The number of organic contaminants found in rivers and lakes continues to rise, and part of this contamination gets transferred into sediments. Analytical methods to detect problematic substances in the environment often use mass spectrometry coupled with chromatography. Here we reviewed a set of 163 articles and compiled the relevant information into a comprehensive database for analysing organic contaminants in continental sediments including suspended particulate matter and surface and bottom sediments in lakes, rivers and estuaries. We found 1204 compounds detected at least once in sediments, and classified them into 11 categories, i.e. hydrocarbons, flame retardants, polychlorinated biphenyls (PCB), plasticizers, per- and poly-fluoroalkyl substances (PFAS), organochlorines (OCP) and other pesticides, pharmaceuticals, hormones, personal care products (PCP), and other contaminants. Concentrations of these compounds varied from a few ng to several mg/kg of dry sediment. Even hydrophilic compounds were detected in high concentrations. Well-known hydrophobic and persistent contaminants tend to be analysed with mass spectrometry coupled to gas chromatography (GC-MS) whereas contaminants of emerging concern (CEC) are usually analysed with liquid chromatography– mass spectrometry (LC-MS). Suspect screening and non-target analysis (NTA), which use high-resolution mass spectrometry, are still scarcely used on sediment but hold promise for gaining deeper knowledge of organic contamination in aquatic environments. [Display omitted] •Continental sediments store a wide array of organic contaminants.•Even highly hydrophilic compounds have been detected at high concentrations.•LC-HRMS is the method of choice to explore contaminants of emerging concerns.•Non-target analysis can help gain deeper knowledge of aquatic contaminants.