Elucidation of Switching Mechanisms in Memristive Junctions Integrating a Iron(II)‐Ter Pyridine Diazoted Complex

An original way of elaborating vertical metal/molecules/metal memristive junctions through diazonium electrografting of the organic layer and inkjet‐printed top electrodes is reported here. The molecule of interest is a FeII coordination complex with ter‐pyridine ligands, having a diazonium anchorin...

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Published in:Advanced electronic materials 2025-02, Vol.11 (2), p.n/a
Main Authors: Jubert Tomasso, Camille, Petenzi, Thomas, Tidu, Anna, Boukraa, Rassen, Russi, Sofia, Mattana, Giorgio, Gautier, Christelle, Breton, Tony, Lucas, Ivan T., Perrot, Hubert, Fillaud, Laure
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Chemical Sciences
electrografting
organic memristor
spectroelectrochemistry
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container_issue 2
container_start_page
container_title Advanced electronic materials
container_volume 11
creator Jubert Tomasso, Camille
Petenzi, Thomas
Tidu, Anna
Boukraa, Rassen
Russi, Sofia
Mattana, Giorgio
Gautier, Christelle
Breton, Tony
Lucas, Ivan T.
Perrot, Hubert
Fillaud, Laure
description An original way of elaborating vertical metal/molecules/metal memristive junctions through diazonium electrografting of the organic layer and inkjet‐printed top electrodes is reported here. The molecule of interest is a FeII coordination complex with ter‐pyridine ligands, having a diazonium anchoring group. The resulting junction exhibits a memristive behavior characterized by a high ON/OFF ratio and plasticity property. Through the application of advanced techniques such as UV–vis and Raman time‐resolved spectroelectrochemistry, the study demonstrates the significant role of switchable azo bonds derived from diazo electrografting in memristive behavior. An original way of elaborating vertical memristive junctions through diazonium electrografting of the organic layer and inkjet‐printed top electrodes is reported here. The resulting junction exhibits a memristive behavior characterized by a high ON/OFF ratio and plasticity property. Through the application of advanced techniques, the study demonstrates the significant role of switchable azo bonds in memristive behavior.
doi_str_mv 10.1002/aelm.202400350
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subjects Chemical Sciences
electrografting
organic memristor
spectroelectrochemistry
title Elucidation of Switching Mechanisms in Memristive Junctions Integrating a Iron(II)‐Ter Pyridine Diazoted Complex
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