Slow magnetic relaxation in a heteroleptic anilate-based Dy III metal-organic framework

Novel heteroleptic anilate-based lanthanide MOFs (Ln = Tb, Dy, Ho) have been obtained under hydrothermal conditions by the ancillary ligand synthetic strategy. These structurally isomorphous species contain octacoordinated Ln ions with coordination polyhedra approaching an ideal symmetry, best descr...

Full description

Saved in:
Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2024-08, Vol.53 (34), p.14265-14271
Main Authors: Oggianu, Mariangela, Bertolotti, Federica, Manna, Fabio, Congiu, Francesco, Cappai, Antonio, Melis, Claudio, Concas, Giorgio, Avarvari, Narcis, Masciocchi, Norberto, Mercuri, Maria Laura
Format: Article
Language:English
Subjects:
Chemical Sciences
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites cdi_FETCH-LOGICAL-c920-a1c5d67cdca3dde63bc42470038d05c2162cc8a81744a2633f127a7316307f353
container_end_page 14271
container_issue 34
container_start_page 14265
container_title Dalton transactions : an international journal of inorganic chemistry
container_volume 53
creator Oggianu, Mariangela
Bertolotti, Federica
Manna, Fabio
Congiu, Francesco
Cappai, Antonio
Melis, Claudio
Concas, Giorgio
Avarvari, Narcis
Masciocchi, Norberto
Mercuri, Maria Laura
description Novel heteroleptic anilate-based lanthanide MOFs (Ln = Tb, Dy, Ho) have been obtained under hydrothermal conditions by the ancillary ligand synthetic strategy. These structurally isomorphous species contain octacoordinated Ln ions with coordination polyhedra approaching an ideal symmetry, best described by a distorted biaugmented trigonal prismatic geometry. In the whole series, only the Dy-MOF exhibits SMM behaviour.
doi_str_mv 10.1039/D4DT01979B
format article
fullrecord <record><control><sourceid>pubmed_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_04797466v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>39132810</sourcerecordid><originalsourceid>FETCH-LOGICAL-c920-a1c5d67cdca3dde63bc42470038d05c2162cc8a81744a2633f127a7316307f353</originalsourceid><addsrcrecordid>eNpFkE1PAjEQhhujEUQv_gDTqyar_dp2e0RQ2YTEgyQeN0PbhdXulnQXkX8vBMXTvJn3mTk8CF1Tck8J1w9jMZ4RqpV-PEF9KpRKNOPi9JiZ7KGLtv0ghDGSsnPU45pyllHSR-9vPmxwDYvGdZXB0Xn4hq4KDa4aDHjpOheDd6t9CU3loXPJHFpn8XiL8zzHtevAJyEudq3BZYTabUL8vERnJfjWXf3OAZo9P81Gk2T6-pKPhtPEaEYSoCa1UhlrgFvrJJ8bwYQihGeWpIZRyYzJIKNKCGCS85IyBYpTyYkqecoH6Pbwdgm-WMWqhrgtAlTFZDgt9jsilFZCyi-6Y-8OrImhbaMrjweUFHuRxb_IHXxzgFfree3sEf0zx38A9DRsJQ</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Slow magnetic relaxation in a heteroleptic anilate-based Dy III metal-organic framework</title><source>Royal Society of Chemistry</source><creator>Oggianu, Mariangela ; Bertolotti, Federica ; Manna, Fabio ; Congiu, Francesco ; Cappai, Antonio ; Melis, Claudio ; Concas, Giorgio ; Avarvari, Narcis ; Masciocchi, Norberto ; Mercuri, Maria Laura</creator><creatorcontrib>Oggianu, Mariangela ; Bertolotti, Federica ; Manna, Fabio ; Congiu, Francesco ; Cappai, Antonio ; Melis, Claudio ; Concas, Giorgio ; Avarvari, Narcis ; Masciocchi, Norberto ; Mercuri, Maria Laura</creatorcontrib><description>Novel heteroleptic anilate-based lanthanide MOFs (Ln = Tb, Dy, Ho) have been obtained under hydrothermal conditions by the ancillary ligand synthetic strategy. These structurally isomorphous species contain octacoordinated Ln ions with coordination polyhedra approaching an ideal symmetry, best described by a distorted biaugmented trigonal prismatic geometry. In the whole series, only the Dy-MOF exhibits SMM behaviour.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/D4DT01979B</identifier><identifier>PMID: 39132810</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Chemical Sciences</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2024-08, Vol.53 (34), p.14265-14271</ispartof><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c920-a1c5d67cdca3dde63bc42470038d05c2162cc8a81744a2633f127a7316307f353</cites><orcidid>0000-0003-3422-1066 ; 0000-0002-5768-8403 ; 0000-0002-6001-9040 ; 0009-0002-5246-1952 ; 0000-0001-9970-4494 ; 0000-0002-6579-4492 ; 0000-0001-9921-2350 ; 0000-0002-0618-8329 ; 0000-0002-4816-427X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/39132810$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://univ-angers.hal.science/hal-04797466$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Oggianu, Mariangela</creatorcontrib><creatorcontrib>Bertolotti, Federica</creatorcontrib><creatorcontrib>Manna, Fabio</creatorcontrib><creatorcontrib>Congiu, Francesco</creatorcontrib><creatorcontrib>Cappai, Antonio</creatorcontrib><creatorcontrib>Melis, Claudio</creatorcontrib><creatorcontrib>Concas, Giorgio</creatorcontrib><creatorcontrib>Avarvari, Narcis</creatorcontrib><creatorcontrib>Masciocchi, Norberto</creatorcontrib><creatorcontrib>Mercuri, Maria Laura</creatorcontrib><title>Slow magnetic relaxation in a heteroleptic anilate-based Dy III metal-organic framework</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>Novel heteroleptic anilate-based lanthanide MOFs (Ln = Tb, Dy, Ho) have been obtained under hydrothermal conditions by the ancillary ligand synthetic strategy. These structurally isomorphous species contain octacoordinated Ln ions with coordination polyhedra approaching an ideal symmetry, best described by a distorted biaugmented trigonal prismatic geometry. In the whole series, only the Dy-MOF exhibits SMM behaviour.</description><subject>Chemical Sciences</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNpFkE1PAjEQhhujEUQv_gDTqyar_dp2e0RQ2YTEgyQeN0PbhdXulnQXkX8vBMXTvJn3mTk8CF1Tck8J1w9jMZ4RqpV-PEF9KpRKNOPi9JiZ7KGLtv0ghDGSsnPU45pyllHSR-9vPmxwDYvGdZXB0Xn4hq4KDa4aDHjpOheDd6t9CU3loXPJHFpn8XiL8zzHtevAJyEudq3BZYTabUL8vERnJfjWXf3OAZo9P81Gk2T6-pKPhtPEaEYSoCa1UhlrgFvrJJ8bwYQihGeWpIZRyYzJIKNKCGCS85IyBYpTyYkqecoH6Pbwdgm-WMWqhrgtAlTFZDgt9jsilFZCyi-6Y-8OrImhbaMrjweUFHuRxb_IHXxzgFfree3sEf0zx38A9DRsJQ</recordid><startdate>20240827</startdate><enddate>20240827</enddate><creator>Oggianu, Mariangela</creator><creator>Bertolotti, Federica</creator><creator>Manna, Fabio</creator><creator>Congiu, Francesco</creator><creator>Cappai, Antonio</creator><creator>Melis, Claudio</creator><creator>Concas, Giorgio</creator><creator>Avarvari, Narcis</creator><creator>Masciocchi, Norberto</creator><creator>Mercuri, Maria Laura</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0003-3422-1066</orcidid><orcidid>https://orcid.org/0000-0002-5768-8403</orcidid><orcidid>https://orcid.org/0000-0002-6001-9040</orcidid><orcidid>https://orcid.org/0009-0002-5246-1952</orcidid><orcidid>https://orcid.org/0000-0001-9970-4494</orcidid><orcidid>https://orcid.org/0000-0002-6579-4492</orcidid><orcidid>https://orcid.org/0000-0001-9921-2350</orcidid><orcidid>https://orcid.org/0000-0002-0618-8329</orcidid><orcidid>https://orcid.org/0000-0002-4816-427X</orcidid></search><sort><creationdate>20240827</creationdate><title>Slow magnetic relaxation in a heteroleptic anilate-based Dy III metal-organic framework</title><author>Oggianu, Mariangela ; Bertolotti, Federica ; Manna, Fabio ; Congiu, Francesco ; Cappai, Antonio ; Melis, Claudio ; Concas, Giorgio ; Avarvari, Narcis ; Masciocchi, Norberto ; Mercuri, Maria Laura</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c920-a1c5d67cdca3dde63bc42470038d05c2162cc8a81744a2633f127a7316307f353</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Chemical Sciences</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Oggianu, Mariangela</creatorcontrib><creatorcontrib>Bertolotti, Federica</creatorcontrib><creatorcontrib>Manna, Fabio</creatorcontrib><creatorcontrib>Congiu, Francesco</creatorcontrib><creatorcontrib>Cappai, Antonio</creatorcontrib><creatorcontrib>Melis, Claudio</creatorcontrib><creatorcontrib>Concas, Giorgio</creatorcontrib><creatorcontrib>Avarvari, Narcis</creatorcontrib><creatorcontrib>Masciocchi, Norberto</creatorcontrib><creatorcontrib>Mercuri, Maria Laura</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Oggianu, Mariangela</au><au>Bertolotti, Federica</au><au>Manna, Fabio</au><au>Congiu, Francesco</au><au>Cappai, Antonio</au><au>Melis, Claudio</au><au>Concas, Giorgio</au><au>Avarvari, Narcis</au><au>Masciocchi, Norberto</au><au>Mercuri, Maria Laura</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Slow magnetic relaxation in a heteroleptic anilate-based Dy III metal-organic framework</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2024-08-27</date><risdate>2024</risdate><volume>53</volume><issue>34</issue><spage>14265</spage><epage>14271</epage><pages>14265-14271</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Novel heteroleptic anilate-based lanthanide MOFs (Ln = Tb, Dy, Ho) have been obtained under hydrothermal conditions by the ancillary ligand synthetic strategy. These structurally isomorphous species contain octacoordinated Ln ions with coordination polyhedra approaching an ideal symmetry, best described by a distorted biaugmented trigonal prismatic geometry. In the whole series, only the Dy-MOF exhibits SMM behaviour.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>39132810</pmid><doi>10.1039/D4DT01979B</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-3422-1066</orcidid><orcidid>https://orcid.org/0000-0002-5768-8403</orcidid><orcidid>https://orcid.org/0000-0002-6001-9040</orcidid><orcidid>https://orcid.org/0009-0002-5246-1952</orcidid><orcidid>https://orcid.org/0000-0001-9970-4494</orcidid><orcidid>https://orcid.org/0000-0002-6579-4492</orcidid><orcidid>https://orcid.org/0000-0001-9921-2350</orcidid><orcidid>https://orcid.org/0000-0002-0618-8329</orcidid><orcidid>https://orcid.org/0000-0002-4816-427X</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1477-9226
ispartof Dalton transactions : an international journal of inorganic chemistry, 2024-08, Vol.53 (34), p.14265-14271
issn 1477-9226
1477-9234
language eng
recordid cdi_hal_primary_oai_HAL_hal_04797466v1
source Royal Society of Chemistry
subjects Chemical Sciences
title Slow magnetic relaxation in a heteroleptic anilate-based Dy III metal-organic framework
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-02T14%3A34%3A17IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pubmed_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Slow%20magnetic%20relaxation%20in%20a%20heteroleptic%20anilate-based%20Dy%20III%20metal-organic%20framework&rft.jtitle=Dalton%20transactions%20:%20an%20international%20journal%20of%20inorganic%20chemistry&rft.au=Oggianu,%20Mariangela&rft.date=2024-08-27&rft.volume=53&rft.issue=34&rft.spage=14265&rft.epage=14271&rft.pages=14265-14271&rft.issn=1477-9226&rft.eissn=1477-9234&rft_id=info:doi/10.1039/D4DT01979B&rft_dat=%3Cpubmed_hal_p%3E39132810%3C/pubmed_hal_p%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c920-a1c5d67cdca3dde63bc42470038d05c2162cc8a81744a2633f127a7316307f353%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/39132810&rfr_iscdi=true