Tuning photochemical properties of phosphorus(v) porphyrin photosensitizers

Photosensitizing and emission properties of P(v) porphyrins were studied. The nature of the axial ligands, occupying the apical position on the P centre adopting an octahedral coordination geometry, strongly influences singlet oxygen generation and charge transfer and allows switching between the tw...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2017, Vol.53 (71), p.9918-9921
Main Authors: Meshkov, Ivan N, Bulach, Véronique, Gorbunova, Yulia G, Gostev, Fedor E, Nadtochenko, Victor A, Tsivadze, Aslan Yu, Hosseini, Mir Wais
Format: Article
Language:English
Subjects:
Chemical Sciences
or physical chemistry
Organic chemistry
Theoretical and
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Summary:Photosensitizing and emission properties of P(v) porphyrins were studied. The nature of the axial ligands, occupying the apical position on the P centre adopting an octahedral coordination geometry, strongly influences singlet oxygen generation and charge transfer and allows switching between the two processes.
ISSN:1359-7345
1364-548X
DOI:10.1039/c7cc06052a