Hypervalent zinc(I) complexes with an NNNN -macrocycle: C-H bond activation across the zinc(I)-zinc(I) bond

Hetero- and homoleptic dinuclear zinc(I) complexes containing the macrocycle Me TACD ( , ', '', '''-1,4,7,10-tetramethylcyclododecane) were prepared; the heteroleptic complex [(Me TACD)Zn-ZnCp*] reacted with activated hydrocarbons R-H (R = CH CN, CCPh) to give the corr...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2024-10, Vol.60 (80), p.11359-11362
Main Authors: Mahawar, Pritam, Rajeshkumar, Thayalan, Spaniol, Thomas P, Maron, Laurent, Okuda, Jun
Format: Article
Language:English
Subjects:
Chemical Sciences
Hydrogen bonds
Organic chemistry
Zinc compounds
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Hetero- and homoleptic dinuclear zinc(I) complexes containing the macrocycle Me TACD ( , ', '', '''-1,4,7,10-tetramethylcyclododecane) were prepared; the heteroleptic complex [(Me TACD)Zn-ZnCp*] reacted with activated hydrocarbons R-H (R = CH CN, CCPh) to give the corresponding hydrocarbyl zinc(II) complexes [(Me TACD)ZnR] .
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/d4cc04266b