Hypervalent zinc(I) complexes with an NNNN -macrocycle: C-H bond activation across the zinc(I)-zinc(I) bond

Hetero- and homoleptic dinuclear zinc(I) complexes containing the macrocycle Me TACD ( , ', '', '''-1,4,7,10-tetramethylcyclododecane) were prepared; the heteroleptic complex [(Me TACD)Zn-ZnCp*] reacted with activated hydrocarbons R-H (R = CH CN, CCPh) to give the corr...

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Published in:Chemical communications (Cambridge, England) England), 2024-10, Vol.60 (80), p.11359-11362
Main Authors: Mahawar, Pritam, Rajeshkumar, Thayalan, Spaniol, Thomas P, Maron, Laurent, Okuda, Jun
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Language:English
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Chemical Sciences
Hydrogen bonds
Organic chemistry
Zinc compounds
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Rajeshkumar, Thayalan
Spaniol, Thomas P
Maron, Laurent
Okuda, Jun
description Hetero- and homoleptic dinuclear zinc(I) complexes containing the macrocycle Me TACD ( , ', '', '''-1,4,7,10-tetramethylcyclododecane) were prepared; the heteroleptic complex [(Me TACD)Zn-ZnCp*] reacted with activated hydrocarbons R-H (R = CH CN, CCPh) to give the corresponding hydrocarbyl zinc(II) complexes [(Me TACD)ZnR] .
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subjects Chemical Sciences
Hydrogen bonds
Organic chemistry
Zinc compounds
title Hypervalent zinc(I) complexes with an NNNN -macrocycle: C-H bond activation across the zinc(I)-zinc(I) bond
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