Healable Supramolecular Polymers as Organic Metals

• Published in: Journal of the American Chemical Society 2014-08, Vol.136 (32), p.11382-11388
• Main Authors: Armao, Joseph J, Maaloum, Mounir, Ellis, Thomas, Fuks, Gad, Rawiso, Michel, Moulin, Emilie, Giuseppone, Nicolas
• Format: Article
• Language: English
• Subjects: Chemical Sciences; Polymers
• ISSN: 0002-7863; 1520-5126
• DOI: 10.1021/ja5044006

Organic materials exhibiting metallic behavior are promising for numerous applications ranging from printed nanocircuits to large area electronics. However, the optimization of electronic conduction in organic metals such as charge-transfer salts or doped conjugated polymers requires high crystallinity, which is detrimental to their processability. To overcome this problem, the combination of the electronic properties of metal-like materials with the mechanical properties of soft self-assembled systems is attractive but necessitates the absence of structural defects in a regular lattice. Here we describe a one-dimensional supramolecular polymer in which photoinduced through-space charge-transfer complexes lead to highly coherent domains with delocalized electronic states displaying metallic behavior. We also reveal that diffusion of supramolecular polarons in the nanowires repairs structural defects thereby improving their conduction. The ability to access metallic properties from mendable self-assemblies extends the current understanding of both fields and opens a wide range of processing techniques for applications in organic electronics.