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X-ray diffuse scattering and magnetic resonance: a study of structural phase transitions in perylene radical cation salts
The quasi-one-dimensional organic conductors di-perylene hexafluorophosphate and -antimonate undergo three and two structural phase transitions below room temperature, respectively. The unequivocal structural proof of the Peierls transition at T p in both compounds is provided by X-ray diffuse scatt...
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| Published in: | Synthetic metals 2000, Vol.108 (1), p.21-26 |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c370t-402602c3cd8b9a9f9988f9e137158c4d40e430b30a57f4aa3689cf4c8c387bb33 |
| container_end_page | 26 |
| container_issue | 1 |
| container_start_page | 21 |
| container_title | Synthetic metals |
| container_volume | 108 |
| creator | Buschhaus, Carsten Moret, Roger Ravy, Sylvain Dormann, Elmar |
| description | The quasi-one-dimensional organic conductors di-perylene hexafluorophosphate and -antimonate undergo three and two structural phase transitions below room temperature, respectively. The unequivocal structural proof of the Peierls transition at
T
p in both compounds is provided by X-ray diffuse scattering experiments. The characterization of the structural phase transitions above
T
p is done using the analysis of X-ray patterns together with previously known ESR results. The combined techniques offer new insight into the relative displacements and rotations of the perylene stacks. The relationship between the Peierls transition and the precursor transitions is discussed. |
| doi_str_mv | 10.1016/S0379-6779(99)00157-5 |
| format | article |
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T
p in both compounds is provided by X-ray diffuse scattering experiments. The characterization of the structural phase transitions above
T
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T
p in both compounds is provided by X-ray diffuse scattering experiments. The characterization of the structural phase transitions above
T
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T
p in both compounds is provided by X-ray diffuse scattering experiments. The characterization of the structural phase transitions above
T
p is done using the analysis of X-ray patterns together with previously known ESR results. The combined techniques offer new insight into the relative displacements and rotations of the perylene stacks. The relationship between the Peierls transition and the precursor transitions is discussed.</abstract><cop>Lausanne</cop><cop>Amsterdam</cop><cop>New York, NY</cop><pub>Elsevier B.V</pub><doi>10.1016/S0379-6779(99)00157-5</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-4210-9410</orcidid></addata></record> |
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| identifier | ISSN: 0379-6779 |
| ispartof | Synthetic metals, 2000, Vol.108 (1), p.21-26 |
| issn | 0379-6779 1879-3290 |
| language | eng |
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| source | ScienceDirect Freedom Collection |
| subjects | Condensed Matter Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Crystalline state (including molecular motions in solids) Crystallographic aspects of phase transformations pressure effects Electron states Exact sciences and technology Materials Science Metal-insulator transitions and other electronic transitions Peierls transition Physics Quasi-one-dimensional conductors Structural properties Structure of solids and liquids crystallography |
| title | X-ray diffuse scattering and magnetic resonance: a study of structural phase transitions in perylene radical cation salts |
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