The Absorption Spectrum of the Free NCO Radical

Two systems of absorption bands have been observed in the visible and ultra-violet regions of the spectrum during the flash photolysis of several organic cyanates, and have been photographed under high resolution with long absorbing paths. Extensive vibrational and rotational analyses have been carr...

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Bibliographic Details
Published in:Philosophical transactions of the Royal Society of London. Series A: Mathematical and physical sciences 1960-01, Vol.252 (1007), p.165-192
Main Author: Dixon, Richard Newland
Format: Article
Language:English
Subjects:
Absorption spectra
Bending
Electrons
Free radicals
Ground state
Mathematical constants
Molecules
Rotational spectra
Rotational states
Spectral bands
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Summary:Two systems of absorption bands have been observed in the visible and ultra-violet regions of the spectrum during the flash photolysis of several organic cyanates, and have been photographed under high resolution with long absorbing paths. Extensive vibrational and rotational analyses have been carried out for the bands of one system and show that the spectrum is due to an electronic transition A(2Z+)
ISSN:1364-503X
0080-4614
1471-2962
2054-0272
DOI:10.1098/rsta.1960.0003