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N incorporation into ALD HfO/sub 2/ gate dielectric using ion implantation [MOSFET application]

A fabrication process for HfON, using ion implantation of N/sub 2/ in ALD HfO/sub 2/, was demonstrated. Results showed that a good quality HfON could be formed by N/sub 2/ implantation, which suggests nitrogen implantation can be an alternative high-k nitridation technique. This process was successf...

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Main Authors: Li, H.-J., Pompl, T., Young, C., Rhoad, T., Saulters, J., Peterson, J., Gardner, M., Brown, G.A., Bersuker, G., Zeitzoff, P.M., Price, J., Hung, P.Y., Diebold, A., Huff, H.R.
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creator Li, H.-J.
Pompl, T.
Young, C.
Rhoad, T.
Saulters, J.
Peterson, J.
Gardner, M.
Brown, G.A.
Bersuker, G.
Zeitzoff, P.M.
Price, J.
Hung, P.Y.
Diebold, A.
Huff, H.R.
description A fabrication process for HfON, using ion implantation of N/sub 2/ in ALD HfO/sub 2/, was demonstrated. Results showed that a good quality HfON could be formed by N/sub 2/ implantation, which suggests nitrogen implantation can be an alternative high-k nitridation technique. This process was successfully integrated into a traditional CMOS flow and the electrical and reliability results of HfON, as compared to HfO/sub 2/, showed 10 times less Vt shift in the pulsed Id-Vg measurement and up to 70% gate leakage reduction. In addition, EOT, electron/hole mobility, TDDB and subthreshold slope of HfON also performed better than those of HfO/sub 2/. A model is proposed to explain the result by attributing the improvement to the reduction of defect states (oxygen vacancies) in the HfO/sub 2/ film by the presence of N in the HfON film.
doi_str_mv 10.1109/DRC.2004.1367760
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identifier ISSN: 1548-3770
ispartof Conference Digest [Includes 'Late News Papers' volume] Device Research Conference, 2004. 62nd DRC, 2004, p.15-16 vol.1
issn 1548-3770
2640-6853
language eng
recordid cdi_ieee_primary_1367760
source IEEE Xplore All Conference Series
subjects CMOS process
Electric variables measurement
Fabrication
Fluid flow measurement
Hafnium oxide
High K dielectric materials
High-K gate dielectrics
Ion implantation
Nitrogen
Pulse measurements
title N incorporation into ALD HfO/sub 2/ gate dielectric using ion implantation [MOSFET application]
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