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X-Ray Photoelectron Spectroscopy, Magnetic and Dielectric Studies of PbFe1/2Nb1/2O3 Single Crystals
X-ray photoelectron spectroscopy (XPS), magnetic and dielectric studies were performed for flux grown PbFe 1/2 Nb 1/2 O 3 (PFN) single crystals. The core level XPS spectra show that the Pb, Nb and O ions exist in one valence state while Fe ions in two Fe 2+ and Fe 3+ states. Temperature dependences...
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| Published in: | Ferroelectrics 2009-01, Vol.391 (1), p.114-121 |
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| Main Authors: | , , |
| Format: | Article |
| Language: | English |
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| container_end_page | 121 |
| container_issue | 1 |
| container_start_page | 114 |
| container_title | Ferroelectrics |
| container_volume | 391 |
| creator | Kania, A. Talik, E. Kruczek, M. |
| description | X-ray photoelectron spectroscopy (XPS), magnetic and dielectric studies were performed for flux grown PbFe
1/2
Nb
1/2
O
3
(PFN) single crystals. The core level XPS spectra show that the Pb, Nb and O ions exist in one valence state while Fe ions in two Fe
2+
and Fe
3+
states. Temperature dependences of magnetic susceptibility reveals maximum at 10 K (ZFC) and anomaly at T
N
= 156 K related to AFM-PM transition. Dielectric and pyroelectric studies point to two ferroelectric phase transitions at 356 K and 376 K. The influence of appearance of the Fe
2+
state on magnetic and semiconductor properties of PFN is discussed. |
| doi_str_mv | 10.1080/00150190903001805 |
| format | article |
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1/2
Nb
1/2
O
3
(PFN) single crystals. The core level XPS spectra show that the Pb, Nb and O ions exist in one valence state while Fe ions in two Fe
2+
and Fe
3+
states. Temperature dependences of magnetic susceptibility reveals maximum at 10 K (ZFC) and anomaly at T
N
= 156 K related to AFM-PM transition. Dielectric and pyroelectric studies point to two ferroelectric phase transitions at 356 K and 376 K. The influence of appearance of the Fe
2+
state on magnetic and semiconductor properties of PFN is discussed.</description><identifier>ISSN: 0015-0193</identifier><identifier>EISSN: 1563-5112</identifier><identifier>DOI: 10.1080/00150190903001805</identifier><identifier>CODEN: FEROA8</identifier><language>eng</language><publisher>Colchester: Taylor & Francis Group</publisher><subject>1/2 ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; dielectric properties ; Dielectrics, piezoelectrics, and ferroelectrics and their properties ; Exact sciences and technology ; Ferroelectricity and antiferroelectricity ; Lead iron niobate ; magnetic properties ; Magnetic properties and materials ; Magnetically ordered materials: other intrinsic properties ; multiferroics ; PbFe ; Phase transitions and curie point ; Physics ; Pyroelectric and electrocaloric effects ; Saturation moments and magnetic susceptibilities ; X-ray photoelectron spectroscopy</subject><ispartof>Ferroelectrics, 2009-01, Vol.391 (1), p.114-121</ispartof><rights>Copyright Taylor & Francis Group, LLC 2009</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>309,310,314,780,784,789,790,23930,23931,25140,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22685449$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Kania, A.</creatorcontrib><creatorcontrib>Talik, E.</creatorcontrib><creatorcontrib>Kruczek, M.</creatorcontrib><title>X-Ray Photoelectron Spectroscopy, Magnetic and Dielectric Studies of PbFe1/2Nb1/2O3 Single Crystals</title><title>Ferroelectrics</title><description>X-ray photoelectron spectroscopy (XPS), magnetic and dielectric studies were performed for flux grown PbFe
1/2
Nb
1/2
O
3
(PFN) single crystals. The core level XPS spectra show that the Pb, Nb and O ions exist in one valence state while Fe ions in two Fe
2+
and Fe
3+
states. Temperature dependences of magnetic susceptibility reveals maximum at 10 K (ZFC) and anomaly at T
N
= 156 K related to AFM-PM transition. Dielectric and pyroelectric studies point to two ferroelectric phase transitions at 356 K and 376 K. The influence of appearance of the Fe
2+
state on magnetic and semiconductor properties of PFN is discussed.</description><subject>1/2</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>dielectric properties</subject><subject>Dielectrics, piezoelectrics, and ferroelectrics and their properties</subject><subject>Exact sciences and technology</subject><subject>Ferroelectricity and antiferroelectricity</subject><subject>Lead iron niobate</subject><subject>magnetic properties</subject><subject>Magnetic properties and materials</subject><subject>Magnetically ordered materials: other intrinsic properties</subject><subject>multiferroics</subject><subject>PbFe</subject><subject>Phase transitions and curie point</subject><subject>Physics</subject><subject>Pyroelectric and electrocaloric effects</subject><subject>Saturation moments and magnetic susceptibilities</subject><subject>X-ray photoelectron spectroscopy</subject><issn>0015-0193</issn><issn>1563-5112</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFUU1LAzEQDaJgrf4Ab7l4c22y-doFL1KtCtUWq-BtyWaTGtluShLR_femVk89eJk3j3nvwcwAcIrRBUYFGiGEGcIlKhFJbYHYHhhgxknGMM73wWAzz5KAHIKjEN4TJZSWA6BesyfZw_mbi063WkXvOrhY_zRBuXV_Dh_kstPRKii7Bl7brSrRRfxorA7QGTivJxqP8sc6lRmBC9stWw3Hvg9RtuEYHJgE-uQXh-BlcvM8vsums9v78dU0s3nBY0YQzaVmgqta1UYLYZjBgtaYSoM15VoUTU55QzhqOJIa14IyQTUqpZZGIDIEZ9vctQxKtsbLTtlQrb1dSd9Xec4LlpZOOrHV2c44v5KfzrdNFWXfOv9n2rlnFb9icl7-6yQYVZuX7EaQby7hfPM</recordid><startdate>20090101</startdate><enddate>20090101</enddate><creator>Kania, A.</creator><creator>Talik, E.</creator><creator>Kruczek, M.</creator><general>Taylor & Francis Group</general><general>Taylor & Francis</general><scope>IQODW</scope></search><sort><creationdate>20090101</creationdate><title>X-Ray Photoelectron Spectroscopy, Magnetic and Dielectric Studies of PbFe1/2Nb1/2O3 Single Crystals</title><author>Kania, A. ; Talik, E. ; Kruczek, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i286t-3042ae576cbcbfe77f5f174b14af1e46e78d246d360d60ae1b74574e09aeaf703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>1/2</topic><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>dielectric properties</topic><topic>Dielectrics, piezoelectrics, and ferroelectrics and their properties</topic><topic>Exact sciences and technology</topic><topic>Ferroelectricity and antiferroelectricity</topic><topic>Lead iron niobate</topic><topic>magnetic properties</topic><topic>Magnetic properties and materials</topic><topic>Magnetically ordered materials: other intrinsic properties</topic><topic>multiferroics</topic><topic>PbFe</topic><topic>Phase transitions and curie point</topic><topic>Physics</topic><topic>Pyroelectric and electrocaloric effects</topic><topic>Saturation moments and magnetic susceptibilities</topic><topic>X-ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kania, A.</creatorcontrib><creatorcontrib>Talik, E.</creatorcontrib><creatorcontrib>Kruczek, M.</creatorcontrib><collection>Pascal-Francis</collection><jtitle>Ferroelectrics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kania, A.</au><au>Talik, E.</au><au>Kruczek, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>X-Ray Photoelectron Spectroscopy, Magnetic and Dielectric Studies of PbFe1/2Nb1/2O3 Single Crystals</atitle><jtitle>Ferroelectrics</jtitle><date>2009-01-01</date><risdate>2009</risdate><volume>391</volume><issue>1</issue><spage>114</spage><epage>121</epage><pages>114-121</pages><issn>0015-0193</issn><eissn>1563-5112</eissn><coden>FEROA8</coden><abstract>X-ray photoelectron spectroscopy (XPS), magnetic and dielectric studies were performed for flux grown PbFe
1/2
Nb
1/2
O
3
(PFN) single crystals. The core level XPS spectra show that the Pb, Nb and O ions exist in one valence state while Fe ions in two Fe
2+
and Fe
3+
states. Temperature dependences of magnetic susceptibility reveals maximum at 10 K (ZFC) and anomaly at T
N
= 156 K related to AFM-PM transition. Dielectric and pyroelectric studies point to two ferroelectric phase transitions at 356 K and 376 K. The influence of appearance of the Fe
2+
state on magnetic and semiconductor properties of PFN is discussed.</abstract><cop>Colchester</cop><pub>Taylor & Francis Group</pub><doi>10.1080/00150190903001805</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0015-0193 |
| ispartof | Ferroelectrics, 2009-01, Vol.391 (1), p.114-121 |
| issn | 0015-0193 1563-5112 |
| language | eng |
| recordid | cdi_informaworld_taylorfrancis_310_1080_00150190903001805 |
| source | Taylor and Francis Science and Technology Collection |
| subjects | 1/2 Condensed matter: electronic structure, electrical, magnetic, and optical properties dielectric properties Dielectrics, piezoelectrics, and ferroelectrics and their properties Exact sciences and technology Ferroelectricity and antiferroelectricity Lead iron niobate magnetic properties Magnetic properties and materials Magnetically ordered materials: other intrinsic properties multiferroics PbFe Phase transitions and curie point Physics Pyroelectric and electrocaloric effects Saturation moments and magnetic susceptibilities X-ray photoelectron spectroscopy |
| title | X-Ray Photoelectron Spectroscopy, Magnetic and Dielectric Studies of PbFe1/2Nb1/2O3 Single Crystals |
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