The Effect of Triethylene-Tetramine Treatment of Carbon Fibers on Performance of Composites

• Published in: Journal of macromolecular science. Physics 2008-11, Vol.47 (6), p.1142-1147
• Main Authors: PeiXian, Hu, YueFang, Wen, YongGang, Yang, Lang, Liu
• Format: Article
• Language: English
• Subjects: Applied sciences; carbon fibers; Composites; Exact sciences and technology; Forms of application and semi-finished materials; interface; Polymer industry, paints, wood; polymer-matrix composites; SEM; Technology of polymers; XPS
• ISSN: 0022-2348; 1525-609X
• DOI: 10.1080/00222340802403222

Amino groups can be introduced to the surface of carbon fibers (CF) by triethylene-tetramine (TETA) treatment. Carbon fibers coated with triethylene-tetramine (TETA) were treated at 400°C for 30 s in an oxidizing furnace. Differential scanning calorimetry studies showed that the surface functional groups of CF reacted with TETA. The changes of the surface composition and structure of CF were tested by X-ray photoelectron spectrometry (XPS). The interfacial interaction between the resulting CF and an epoxy matrix was also characterized by scanning electron microscopy (SEM) and three-point short-beam shear testing. The XPS results indicate that the number of amino groups on the surface of the CF was significantly increased after being treated with TETA. The interlaminar shear strength (ILSS) of TETA-treated CF-reinforced resin composites (CFRP) was increased by 30% compared with untreated ones, and in the treated CF fracture sections, CFRP pores and carbon fiber pullout were seldom observed. The failure of composites reinforced by treated CF shows a cohesive failure effect in the interface layer.