Efficient and Facile Method for the Nitration of Aromatic Compounds by Nitric Acid in Micellar Media

Aromatic compounds were efficiently nitrated under mild reaction conditions by employing HNO 3 in the presence of anionic (sodium dodecyl sulfate, SDS), cationic (cetyl trimethyl ammonium bromide, CTAB), and nonionic (Triton-X 100) micelles. The reaction rapidly afforded corresponding mononitro deri...

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Bibliographic Details
Published in:Synthetic communications 2009-07, Vol.39 (16), p.2949-2953
Main Authors: Sana, S., Tasneem, Ali, M. Moazzam, Rajanna, K. C., Saiprakash, P. K.
Format: Article
Language:English
Subjects:
CTAB
efficient nitration of aromatic compounds
micellar media
SDS
Triton-X 100
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Summary:Aromatic compounds were efficiently nitrated under mild reaction conditions by employing HNO 3 in the presence of anionic (sodium dodecyl sulfate, SDS), cationic (cetyl trimethyl ammonium bromide, CTAB), and nonionic (Triton-X 100) micelles. The reaction rapidly afforded corresponding mononitro derivatives in fair to good yields with high regioselectivity. This new method offers an environmentally safe reaction condition to minimize the waste products.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397910802711318