Rapid and Regiospecific Phenylthiolation of Some Organic Acids Catalyzed by AlCl3 in the Presence of Excess Anhydrous ZnCl2

Phenylthiolation of some carboxylic acids catalyzed by AlCl 3 in the presence of excess dehydrating agent (ZnCl 2 ) has been achieved. Moreover, regiospecificity was tested of some dioic acids and found to be specific at the aliphatic part of carboxylic functionality.

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Published in:Synthetic communications 2010-01, Vol.40 (14), p.2158-2163
Main Authors: Roy, H. N., Sarker, Ashis K., Mamun, A. H. Al
Format: Article
Language:English
Subjects:
Acids
Dioic acids
phenylthiolation
regiospecific esterification
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creator Roy, H. N.
Sarker, Ashis K.
Mamun, A. H. Al
description Phenylthiolation of some carboxylic acids catalyzed by AlCl 3 in the presence of excess dehydrating agent (ZnCl 2 ) has been achieved. Moreover, regiospecificity was tested of some dioic acids and found to be specific at the aliphatic part of carboxylic functionality.
doi_str_mv 10.1080/00397910903219567
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subjects Acids
Dioic acids
phenylthiolation
regiospecific esterification
title Rapid and Regiospecific Phenylthiolation of Some Organic Acids Catalyzed by AlCl3 in the Presence of Excess Anhydrous ZnCl2
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