Practical and Efficient 1α-Hydroxylation of 4,4-Dimethyl-2-Ene Derivatives in Terpenic Series

The third part of a triptycal synthesis providing 1α-hydroxy compounds, through microbial hydroxylation in position-3 of terpenoid substrates, followed by dehydration to 4,4-dimethyl-2-ene compounds and subsequent allylic hydroxylation by SeO 2 /pyridine N-oxide, is described.

Saved in:
Bibliographic Details
Published in:Synthetic communications 1997-01, Vol.27 (1), p.45-60
Main Authors: Aranda, Gérard, Bertranne-Delahaye, Mireille, Azerad, Robert, Maurs, Michèle, Cortés, Manuel, Ramirez, Hector, Vernal, Gonzalo, Prangé, Thierry
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The third part of a triptycal synthesis providing 1α-hydroxy compounds, through microbial hydroxylation in position-3 of terpenoid substrates, followed by dehydration to 4,4-dimethyl-2-ene compounds and subsequent allylic hydroxylation by SeO 2 /pyridine N-oxide, is described.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397919708004804