Asymmetric Simmons-Smith Cyclopropanation Of α,β-Unsaturated Bornane-2,3-Diol Acetals

Reactionofselected α, β-unsaturated aldehydes with bornane-2-exo,3-cxo-diol has afforded a series of novel, chiral acetals which, on treatment with a Simmons-Smithreagent, undergo diastereoselective(46 - 70 %d.e.) cyclopropanatioa

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Bibliographic Details
Published in:Synthetic communications 1999-06, Vol.29 (11), p.1889-1902
Main Authors: Kaye, Perry T., Molema, Warner E.
Format: Article
Language:English
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Summary:Reactionofselected α, β-unsaturated aldehydes with bornane-2-exo,3-cxo-diol has afforded a series of novel, chiral acetals which, on treatment with a Simmons-Smithreagent, undergo diastereoselective(46 - 70 %d.e.) cyclopropanatioa
ISSN:0039-7911
1532-2432
DOI:10.1080/00397919908086177