Asymmetric Simmons-Smith Cyclopropanation Of α,β-Unsaturated Bornane-2,3-Diol Acetals

Reactionofselected α, β-unsaturated aldehydes with bornane-2-exo,3-cxo-diol has afforded a series of novel, chiral acetals which, on treatment with a Simmons-Smithreagent, undergo diastereoselective(46 - 70 %d.e.) cyclopropanatioa

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Published in:Synthetic communications 1999-06, Vol.29 (11), p.1889-1902
Main Authors: Kaye, Perry T., Molema, Warner E.
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Language:English
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cited_by cdi_FETCH-LOGICAL-c344t-8ef1729753295845c50a40f69425ca6bd639ec74cd96b2b33987951b242606773
cites cdi_FETCH-LOGICAL-c344t-8ef1729753295845c50a40f69425ca6bd639ec74cd96b2b33987951b242606773
container_end_page 1902
container_issue 11
container_start_page 1889
container_title Synthetic communications
container_volume 29
creator Kaye, Perry T.
Molema, Warner E.
description Reactionofselected α, β-unsaturated aldehydes with bornane-2-exo,3-cxo-diol has afforded a series of novel, chiral acetals which, on treatment with a Simmons-Smithreagent, undergo diastereoselective(46 - 70 %d.e.) cyclopropanatioa
doi_str_mv 10.1080/00397919908086177
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title Asymmetric Simmons-Smith Cyclopropanation Of α,β-Unsaturated Bornane-2,3-Diol Acetals
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