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Ferromagnetic interactions in a Zn(II)-nitronyl nitroxide complex with dicyanoaurate(I) bridges
A two-dimensional Zn(II)-nitronyl nitroxide radical complex, Zn(NIT4Py) 2 [Au(CN) 2 ] 2 (NIT4Py = 2-(4′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) was synthesized and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction methods. The complex is monocl...
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| Published in: | Journal of coordination chemistry 2005-12, Vol.58 (18), p.1695-1702 |
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| Main Authors: | , , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c346t-c97d41706fe1b87af2bed908758196010de4c5ea67bd15b3d33844aa4b15acae3 |
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| cites | cdi_FETCH-LOGICAL-c346t-c97d41706fe1b87af2bed908758196010de4c5ea67bd15b3d33844aa4b15acae3 |
| container_end_page | 1702 |
| container_issue | 18 |
| container_start_page | 1695 |
| container_title | Journal of coordination chemistry |
| container_volume | 58 |
| creator | Wang, Shu-Ping Chen, Jing Gao, Dong-Zhao Song, You Wang, Qing-Mei Liao, Dai-Zheng Jiang, Zong-Hui Yan, Shi-Ping |
| description | A two-dimensional Zn(II)-nitronyl nitroxide radical complex, Zn(NIT4Py)
2
[Au(CN)
2
]
2
(NIT4Py = 2-(4′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) was synthesized and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction methods. The complex is monoclinic, space group C2/c, with a = 26.294(9), b = 7.167(2), c = 18.532(6) Å, β = 111.758(5)°, V = 3243.6(18) Å
3
, Z = 4, and R
1
[I > 2σ (I)] = 0.0348, and has an infinite two-dimensional network motif. Magnetic studies showed ferromagnetic coupling between two radicals through Zn(II). |
| doi_str_mv | 10.1080/00958970500239765 |
| format | article |
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2
[Au(CN)
2
]
2
(NIT4Py = 2-(4′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) was synthesized and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction methods. The complex is monoclinic, space group C2/c, with a = 26.294(9), b = 7.167(2), c = 18.532(6) Å, β = 111.758(5)°, V = 3243.6(18) Å
3
, Z = 4, and R
1
[I > 2σ (I)] = 0.0348, and has an infinite two-dimensional network motif. Magnetic studies showed ferromagnetic coupling between two radicals through Zn(II).</description><identifier>ISSN: 0095-8972</identifier><identifier>EISSN: 1029-0389</identifier><identifier>DOI: 10.1080/00958970500239765</identifier><language>eng</language><publisher>Taylor & Francis Group</publisher><subject>Dicyanoaurate(I) ; Ferromagnetic interaction ; Nitronyl nitroxide radical ; Two-dimensional complex ; Zinc(II)</subject><ispartof>Journal of coordination chemistry, 2005-12, Vol.58 (18), p.1695-1702</ispartof><rights>Copyright Taylor & Francis Group, LLC 2005</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c346t-c97d41706fe1b87af2bed908758196010de4c5ea67bd15b3d33844aa4b15acae3</citedby><cites>FETCH-LOGICAL-c346t-c97d41706fe1b87af2bed908758196010de4c5ea67bd15b3d33844aa4b15acae3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Wang, Shu-Ping</creatorcontrib><creatorcontrib>Chen, Jing</creatorcontrib><creatorcontrib>Gao, Dong-Zhao</creatorcontrib><creatorcontrib>Song, You</creatorcontrib><creatorcontrib>Wang, Qing-Mei</creatorcontrib><creatorcontrib>Liao, Dai-Zheng</creatorcontrib><creatorcontrib>Jiang, Zong-Hui</creatorcontrib><creatorcontrib>Yan, Shi-Ping</creatorcontrib><title>Ferromagnetic interactions in a Zn(II)-nitronyl nitroxide complex with dicyanoaurate(I) bridges</title><title>Journal of coordination chemistry</title><description>A two-dimensional Zn(II)-nitronyl nitroxide radical complex, Zn(NIT4Py)
2
[Au(CN)
2
]
2
(NIT4Py = 2-(4′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) was synthesized and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction methods. The complex is monoclinic, space group C2/c, with a = 26.294(9), b = 7.167(2), c = 18.532(6) Å, β = 111.758(5)°, V = 3243.6(18) Å
3
, Z = 4, and R
1
[I > 2σ (I)] = 0.0348, and has an infinite two-dimensional network motif. Magnetic studies showed ferromagnetic coupling between two radicals through Zn(II).</description><subject>Dicyanoaurate(I)</subject><subject>Ferromagnetic interaction</subject><subject>Nitronyl nitroxide radical</subject><subject>Two-dimensional complex</subject><subject>Zinc(II)</subject><issn>0095-8972</issn><issn>1029-0389</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNqFkDFPwzAQhS0EEqXwA9g8tkPgHCdxLLGgikIlJBZYWKKL7RSjxK4cozb_npSyVYjp3dO77056hFwzuGFQwi2AzEspIAdIuRRFfkImDFKZAC_lKZns82RcSM_JRd9_AjDOUzEh1dKE4DtcOxOtotZFE1BF610_Gor03c1Wq3nibAzeDS39GXZWG6p8t2nNjm5t_KDaqgGdx6-A0cxWc1oHq9emvyRnDba9ufrVKXlbPrwunpLnl8fV4v45UTwrYqKk0BkTUDSG1aXAJq2NllCKvGSyAAbaZCo3WIhas7zmmvMyyxCzmuWo0PApYYe7Kvi-D6apNsF2GIaKQbVvqDpqaGTEgbGu8aHDrQ-triIOrQ9NQKdsf0xVcRdH8u5fkv_9-BtrvH-h</recordid><startdate>20051215</startdate><enddate>20051215</enddate><creator>Wang, Shu-Ping</creator><creator>Chen, Jing</creator><creator>Gao, Dong-Zhao</creator><creator>Song, You</creator><creator>Wang, Qing-Mei</creator><creator>Liao, Dai-Zheng</creator><creator>Jiang, Zong-Hui</creator><creator>Yan, Shi-Ping</creator><general>Taylor & Francis Group</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20051215</creationdate><title>Ferromagnetic interactions in a Zn(II)-nitronyl nitroxide complex with dicyanoaurate(I) bridges</title><author>Wang, Shu-Ping ; Chen, Jing ; Gao, Dong-Zhao ; Song, You ; Wang, Qing-Mei ; Liao, Dai-Zheng ; Jiang, Zong-Hui ; Yan, Shi-Ping</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c346t-c97d41706fe1b87af2bed908758196010de4c5ea67bd15b3d33844aa4b15acae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Dicyanoaurate(I)</topic><topic>Ferromagnetic interaction</topic><topic>Nitronyl nitroxide radical</topic><topic>Two-dimensional complex</topic><topic>Zinc(II)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Shu-Ping</creatorcontrib><creatorcontrib>Chen, Jing</creatorcontrib><creatorcontrib>Gao, Dong-Zhao</creatorcontrib><creatorcontrib>Song, You</creatorcontrib><creatorcontrib>Wang, Qing-Mei</creatorcontrib><creatorcontrib>Liao, Dai-Zheng</creatorcontrib><creatorcontrib>Jiang, Zong-Hui</creatorcontrib><creatorcontrib>Yan, Shi-Ping</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Shu-Ping</au><au>Chen, Jing</au><au>Gao, Dong-Zhao</au><au>Song, You</au><au>Wang, Qing-Mei</au><au>Liao, Dai-Zheng</au><au>Jiang, Zong-Hui</au><au>Yan, Shi-Ping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ferromagnetic interactions in a Zn(II)-nitronyl nitroxide complex with dicyanoaurate(I) bridges</atitle><jtitle>Journal of coordination chemistry</jtitle><date>2005-12-15</date><risdate>2005</risdate><volume>58</volume><issue>18</issue><spage>1695</spage><epage>1702</epage><pages>1695-1702</pages><issn>0095-8972</issn><eissn>1029-0389</eissn><abstract>A two-dimensional Zn(II)-nitronyl nitroxide radical complex, Zn(NIT4Py)
2
[Au(CN)
2
]
2
(NIT4Py = 2-(4′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) was synthesized and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction methods. The complex is monoclinic, space group C2/c, with a = 26.294(9), b = 7.167(2), c = 18.532(6) Å, β = 111.758(5)°, V = 3243.6(18) Å
3
, Z = 4, and R
1
[I > 2σ (I)] = 0.0348, and has an infinite two-dimensional network motif. Magnetic studies showed ferromagnetic coupling between two radicals through Zn(II).</abstract><pub>Taylor & Francis Group</pub><doi>10.1080/00958970500239765</doi><tpages>8</tpages></addata></record> |
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| ispartof | Journal of coordination chemistry, 2005-12, Vol.58 (18), p.1695-1702 |
| issn | 0095-8972 1029-0389 |
| language | eng |
| recordid | cdi_informaworld_taylorfrancis_310_1080_00958970500239765 |
| source | Taylor and Francis Science and Technology Collection |
| subjects | Dicyanoaurate(I) Ferromagnetic interaction Nitronyl nitroxide radical Two-dimensional complex Zinc(II) |
| title | Ferromagnetic interactions in a Zn(II)-nitronyl nitroxide complex with dicyanoaurate(I) bridges |
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