Synthesis, crystal structure and characterization of a 1D chain coordination polymer of zinc(II) with aroylamide, [Zn(H2bpb)Cl2] n · CH3OH, (H2bpb = 1,2- bis (3-pyridylcarboxamide)benzene)

A four-coordinate zinc(II) coordination polymer, [ZnCl 2 (H 2 bpb)] n · CH 3 OH (H 2 bpb = 1,2-bis(3-pyridylcarboxylamide)benzene), has been prepared and the crystal structure determined by X-ray diffraction. It crystallizes in the triclinic system, space group with a = 7.898(3) Å, b = 11.792(4) Å,...

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Bibliographic Details
Published in:Journal of coordination chemistry 2008-01, Vol.61 (2), p.285-293
Main Authors: Zhang, Ping, Niu, Yun-Yin, Zhang, Zong-Pei, Zhang, Hong-yun, Li, Zhong-Jun, Niu, Cao-Yuan, Wu, Ben-Lai, Hou, Hong-Wei
Format: Article
Language:English
Subjects:
Coordination polymer
Crystal structure
Fluorescent property
Thermal property
Zinc(II) complex
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Summary:A four-coordinate zinc(II) coordination polymer, [ZnCl 2 (H 2 bpb)] n · CH 3 OH (H 2 bpb = 1,2-bis(3-pyridylcarboxylamide)benzene), has been prepared and the crystal structure determined by X-ray diffraction. It crystallizes in the triclinic system, space group with a = 7.898(3) Å, b = 11.792(4) Å, c = 11.911(4) Å, α = 76.051(4)°, β = 89.919(4)°, γ = 78.267(4)°, V = 1052.9(7) Å, Z = 2. The crystal structure consists of chains of complex zig-zaging along the b lattice translation. Fluorescent and thermal properties of the complex were also investigated.
ISSN:0095-8972
1029-0389
DOI:10.1080/00958970701329183